Journal ArticleDOI
Effect of hydrogen bonds on the thermodynamic behavior of liquid water.
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In this paper, an extension of the van der Waals equation was proposed to incorporate the effects of the network of hydrogen bonds that exist in liquid water, and the resulting model qualitatively predicts the unique thermodynamic properties of water, including those of deeply supercooled states.Abstract:
We propose an extension of the van der Waals equation which is designed to incorporate, in an approximate fashion, the effects of the network of hydrogen bonds that exist in liquid water. The resulting model qualitatively predicts the unique thermodynamic properties of water, including those of the deeply supercooled states. It also reconciles two proposals for the phase behavior of supercooled and stretched water and provides a thermodynamic origin for the observed polymorphism of the amorphous solid form of water.read more
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Journal ArticleDOI
Formation of glasses from liquids and biopolymers.
TL;DR: The onset of a sharp change in ddT( is the Debye-Waller factor and T is temperature) in proteins, which is controversially indentified with the glass transition in liquids, is shown to be general for glass formers and observable in computer simulations of strong and fragile ionic liquids, where it proves to be close to the experimental glass transition temperature.
Journal ArticleDOI
The relationship between liquid, supercooled and glassy water
Osamu Mishima,H. Eugene Stanley +1 more
TL;DR: This article showed that water can exist in two distinct "glassy" forms, low and high density amorphous ice, which may provide the key to understanding some of the puzzling characteristics of cold and supercooled water.
Journal ArticleDOI
Review of the vapour pressures of ice and supercooled water for atmospheric applications
DM Murphy,Thomas Koop +1 more
TL;DR: In this paper, the vapour pressure of ice and supercooled water is reviewed with an emphasis on atmospheric applications, and various parametrizations are given for the vapor pressure, molar heat capacity, and latent heat of both ice and liquid water.
Journal ArticleDOI
Supercooled and glassy water
TL;DR: The authors summarizes the known experimental facts and reviews critically theoretical and computational work aimed at interpreting the observations and providing a unified viewpoint on cold, non-crystalline, metastable states of water.
Journal ArticleDOI
Water Modeled As an Intermediate Element between Carbon and Silicon
Valeria Molinero,Emily B. Moore +1 more
TL;DR: mW mimics the hydrogen-bonded structure of water through the introduction of a nonbond angular dependent term that encourages tetrahedral configurations, and concludes that it is not the nature of the interactions but the connectivity of the molecules that determines the structural and thermodynamic behavior of water.
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