Effect of Pressure on the Reaction Between 3‐Methyl‐1‐p‐tolyl‐triazene and Benzoic Acid; a Kinetic Study.

TLDR: In this paper, the rates of reaction between 3-methyl-1p-tolytriazene and benzoic acid were measured with variation of pressure in chloroform and acetonitrile.

Abstract: Rates of reaction between 3-methyl-1p-tolytriazene and benzoic acid were measured with variation of pressure in chloroform and acetonitrile. Activation volumes were found to be–15 and–4 cm3 mol−1, respectively. The reaction mechanism is discussed in the context of these values.