Journal ArticleDOI
Electrochemical synthesis of metallic complexes of bidentate thiolates containing nitrogen as an additional donor atom
TLDR
In this paper, the authors describe the results obtained by their group on the synthesis of metallic thiolato complexes by the electrochemical oxidation of a sacrificial anode in a non-aqueous solution of the precursor ligand.About:
This article is published in Coordination Chemistry Reviews.The article was published on 1999-10-01. It has received 104 citations till now. The article focuses on the topics: Denticity & Steric effects.read more
Citations
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Recent studies in the coordination chemistry of heterocyclic thiones and thionates
TL;DR: Heterocyclic thioamides usually occurring in their thioketo form are referred to as thiones and their corresponding anions as ‘thionates’.
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Coordination polymers of copper(I) halides and neutral heterocyclic thiones with new coordination modes.
Dan Li,Wen-Juan Shi,Lei Hou +2 more
TL;DR: Reactions of the heterocyclic thione ligand 2,4,6-trimercaptotriazine (H3TMT) with copper(I) halides afforded novel three-dimensional polymers, which crystallized in the cubic space group Pa.
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Electrical conductivity and luminescence in coordination polymers based on copper(I)-halides and sulfur-pyrimidine ligands
TL;DR: The studies of the physical properties of the novel coordination polymers reveal that compounds 3 and 5 present excellent electrical conductivity values at room temperature, while compounds 1, 3, and 5-7 show luminescent strong red emission at roomTemperature.
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Versatility of Heterocyclic Thioamides in the Construction of a Trinuclear Cluster [Cu3I3(dppe)3(SC5H4NH)] and CuI Linear Polymers {Cu6(SC5H4NH)6I6}n·2nCH3CN and {CuI6(SC3H6N2)6X6}n (X = Br, I)
TL;DR: The (mu3-S) modes of bonding of neutral heterocyclic thioamides are first examples, as are trinuclear cluster and linear polymers rare examples in copper chemistry.
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Synthesis of 1D {Cu6(μ3-SC3H6N2)4(μ-SC3H6N2)2(μ-I)2I4}n and 3D {Cu2(μ-SC3H6N2)2(μ-SCN)2}n Polymers with 1,3-Imidazolidine-2-thione: Bond Isomerism in Polymers
TL;DR: In this paper, the reaction of copper iodide with 1, 3-imidazolidine-2-thione (SC3H6N2) in a 1:2 molar ratio (M/L) has formed unusual 1D polymers.
References
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Journal ArticleDOI
Complexes of heterocyclic thione donors
TL;DR: The major ligand abbreviations for heterocyclic thione donors can be found in this paper, where they include triazoline-thiones, trivalines, and trivaline-trivalines.
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Thiolato-complexes of the transition metals
TL;DR: In this article, the authors define three types of thiolato-complexes: terminal, monomeric, and sterically hindered, and three-dimensional clusters with tetrahedral metal centres.
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Complexes of heterocyclic thionates. Part 1. Complexes of monodentate and chelating ligands
TL;DR: In this article, the effect of deprotonation and coordination on the dimensions of parent heterocyclic thiones, especially those of pyridine-2-thione and benzo-1,3-thiazoline-2.
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Transition‐Metal Thiolates: From Molecular Fragments of Sulfidic Solids to Models for Active Centers in Biomolecules
Bernt Krebs,Gerald Henkel +1 more
TL;DR: In this article, the synthesis of polynuclear cagelike homo-and heteroleptic metal-sulfur frameworks, which can often be regarded as “molecular fragments” of the structures of inorganic sulfides, is described.