Journal ArticleDOI
Thiolato-complexes of the transition metals
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In this article, the authors define three types of thiolato-complexes: terminal, monomeric, and sterically hindered, and three-dimensional clusters with tetrahedral metal centres.About:
This article is published in Coordination Chemistry Reviews.The article was published on 1987-02-01. It has received 458 citations till now. The article focuses on the topics: Rhodium & Rhenium.read more
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Complexes of heterocyclic thionates. Part 1. Complexes of monodentate and chelating ligands
TL;DR: In this article, the effect of deprotonation and coordination on the dimensions of parent heterocyclic thiones, especially those of pyridine-2-thione and benzo-1,3-thiazoline-2.
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Copper radionuclides and radiopharmaceuticals in nuclear medicine
TL;DR: The chemistry, radiochemistry, radiobiology, and radiopharmacology of radiopharmaceuticals containing copper radionuclides are reviewed and are likely to be applied more fully in the future.
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Metallothioneins: zinc, cadmium, mercury, and copper thiolates and selenolates mimicking protein active site features--structural aspects and biological implications.
Gerald Henkel,Bernt Krebs +1 more
TL;DR: It is concluded that the long sought role of MT lies in the control of the cellular zinc distribution as a function of the energy state of the cell and not in the widely held belief that MT primarily scavenges radicals or detoxifies metals.
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Complexes of heterocyclic thionates Part 2: complexes of bridging ligands
TL;DR: The bridging behavior of deprotonated heterocyclic thiones is described in this paper, where anions are effective bridging ligands among binuclear, trinuclear, tetranuclear hexanuclear and polynuclear metallic species.
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Copper complexes of heterocyclic thioamides and related ligands
TL;DR: In this paper, a detailed discussion of the structural aspects of these species based upon X-ray data is presented. But emphasis is placed on detailed discussion on the structural properties of the species.
References
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Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds
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Coordination chemistry of thioethers, selenoethers, and telluroethers in transition-metal complexes
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Chemistry of .mu.-dithio-bis(tricarbonyliron), a mimic of organic disulfides. 1. Formation of di-.mu.-thiolate-bis(tricarbonyliron) dianion
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Triple-decker sandwiches
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Properties of Sulfur‐Sulfur Bonds
TL;DR: In this article, the authors show that SS bonds are extraordinarily flexible and have properties that are observed only on isolated occasions for other homonuclear bonds: the bond lengths very between 1.8 and 3.0A, the bond angles between 90 and 180° and the dihedral angles between 0 and 360°; the bond energies amount to up to 430 kJ/mol.