Journal ArticleDOI
Electron paramagnetic resonance and electronic spectral evidence for isomers resulting from basal and axial ligation of bis(hexafluoroacetylacetonato)copper(II) by triphenylphosphine
B. B. Wayland,V. K. Kapur +1 more
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This article is published in Inorganic Chemistry.The article was published on 1974-10-01. It has received 18 citations till now. The article focuses on the topics: Electron paramagnetic resonance & Triphenylphosphine.read more
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Functional mimics of copper enzymes. Synthesis and stereochemical properties of the copper(II) complexes of a trinucleating ligand derived from l-histidine
Laura Santagostini,Michele Gullotti,Roberto Pagliarin,Emanuela Bianchi,Luigi Casella,Enrico Monzani +5 more
TL;DR: In this article, the piperazine-1,4-bis (PHI) ligand was synthesized by a multistep procedure starting from N τ -methyl- l -histidine, and the ligand has two potential tridentate aminobis(imidazole) (A sites), and one bidentate, pingerazine (B sites), binding sites for metal ions and was employed for the synthesis of the binuclear [Cu 2 PHI] 4+ and the trinuclear [cu 3 PHI] 6+ complexes.
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An ESR study of addition species formed between bis(2-thiopyridine N-oxide)Cu(II) and heterocyclic and aliphatic amines
David R. Brown,Douglas X. West +1 more
TL;DR: In this article, a 2.5 × 10 −3 M nitromethane solution of bis(2-thiopyridine Noxide)Cu(II), CuO 2 S 2, have been added stoichiometric amounts of heterocyclic and aliphatic amines.
Journal ArticleDOI
Noncovalent Interaction-Driven Stereoselectivity of Copper(II) Complexes with Cyclodextrin Derivatives of l- and d-Carnosine
TL;DR: D-Carnosine (DCar), the enantiomer of the naturally occurring dipeptide, shows the same properties as those of LCar, but it is not hydrolyzed by carnosinases and the copper(II) binding properties of the new DCar derivative revealed a pronounced difference from the analogous LCar derivative, especially concerning the dimeric species.
Journal ArticleDOI
Chemistry of mercaptopyridines and related ligands. Part 3. Novel examples of copper(II)–tertiary phosphine complexes stabilized by 1-hydroxypyridine-2-thione
TL;DR: In this article, the first air and moisture-stable copper-tertiary phosphine complexes in which CuII is bonded to one halogen, one oxygen, one sulfur and two phosphorus atoms were presented.
Related Papers (5)
The electronic properties and stereochemistry of mono-nuclear complexes of the copper(II) ion
B.J. Hathaway,D.E. Billing +1 more