Journal ArticleDOI
Electron transfer through organic structural units. VII. Reduction of salicylatopentaamminecobalt(III)
Edwin S. Gould,Anthony Liang +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1970-11-01. It has received 5 citations till now. The article focuses on the topics: Electron transfer.read more
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Role of the bridging ligand in inner-sphere electron-transfer reactions
Journal ArticleDOI
Kinetics of Dissociation of Iron(III) Complexes of Tiron in Aqueous Acid.
TL;DR: The kinetics of dissociation of the mono, bis, and tris complexes of Tiron (1,2-dihydroxy-3,5-benzenedisulfonate) have been studied in acidic aqueous solutions in 1.0 M HClO(4)/NaClO (4), as a function of [H(+)] and temperature.
Journal ArticleDOI
Electron transfer reactions in metal ammine complexes—IV: Reduction of some amino acid, aminobenzoic acid and their Schiff base substituted pentaammine Cr(III) complexes at the dropping mercury electrode
R. Bembi,O.P. Tandon +1 more
TL;DR: In this article, it was shown that the contribution of the inner/outer-sphere path is maximum in the case of aminobenzoic acid and minimum in the cases of Schiff bases of amino acid compounds.
Journal ArticleDOI
Electron transfer reactions in metal ammine complexes—III: Reduction of amino benzoic acid and their Schiff base substituted petaammine Cr(III) complexes by Cr(II)
R. Bembi,O.P. Tandon +1 more
TL;DR: In this paper, the steric shielding effect of the NH 3 + group to adjacent attack by Cr(II) perchlorates was investigated and the H + ion dependence and the higher rate of reduction of the o -amino benzoato complex at low H+ ion concentrations can be accounted for on the basis of chelation in the transition state.
Related Papers (3)
Electron transfer through organic structural units. XIX. Rate enhancement by neighboring groups in reductions with europium(II)
P. K. Thamburaj,Edwin S. Gould +1 more
Electron transfer through organic structural units part 19, rate enhancement by neighboring groups in reductions with europium(ii)
P. K. Thamburaj,Edwin S. Gould +1 more