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ESR study of Ag2+ ions in KNO3

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TLDR
In this article, the presence of Ag 2+ centres was detected in γ-irradiated silver-doped potassium nitrate at LNT and principal values of g - and A -tensors were obtained.
Abstract
ESR studies on γ-irradiated silver-doped potassium nitrate at LNT indicated the presence of Ag 2+ centres. Principal values of g - and A -tensors are obtained. Admixture coefficients of d-orbitals have been calculated. On warming the sample the signals due to Ag 2+ centres disappeared at 140 K.

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Citations
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Real and Hypothetical Intermediate-Valence AgII/AgIII and AgII/AgI Fluoride Systems as Potential Superconductors

TL;DR: The crystal structures and magnetic properties of the roughly one hundred binary, ternary, and quaternary AgII and AgIII fluorides in the solid state are examined to suggest that properly hole- or electron-doped AgII fluorides might be good BCS-type superconductors.
Journal ArticleDOI

Physicochemical characterization and catalytic performance of 10% Ag/CeO2 catalysts prepared by impregnation and deposition–precipitation

TL;DR: In this article, two silver-cerium oxide samples (Ag 10 ¼wt.%) were prepared by two different methods: impregnation and deposition-precipitation.
Journal ArticleDOI

Electron and hole traps in Ag-doped lithium tetraborate (Li2B4O7) crystals

TL;DR: In this paper, electron paramagnetic resonance (EPR), electron-nuclear double resonance (ENDOR), and thermoluminescence (TL) were used to characterize the primary electron and hole trapping centers in a lithium tetraborate (Li2B4O7) crystal doped with Ag.
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Electron paramagnetic resonance and thermoluminescence study of Ag2+ ions in Li2B4O7 crystals

TL;DR: In this article, the effects of ionizing radiation on Ag-doped lithium tetraborate (Li2B4O7) crystals were investigated using EPR angular dependences.
References
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Journal ArticleDOI

Covalency and Electronic Structure of Cu2+ in ZnF2 by EPR

TL;DR: In this article, the EPR spectrum of copper doped in zinc fluoride has been analyzed and the observed g values led by a new method to a determination of the coefficients of the Kramer's doublet.
Journal ArticleDOI

Paramagnetic resonance of the Ag2+ ion in irradiated alkali chlorides

TL;DR: In this article, a paramagnetic resonance was studied for Ag in the 4d 9 configuration substituting for alkali ions in alkali chlorides, and two spectra were observed corresponding to the low and high temperature modifications of the same spectrum under a "dynamical" Jahn-Teller distortion.
Journal ArticleDOI

ESR of X‐Irradiated Silver Nitrate

TL;DR: In this paper, four paramagnetic species have been detected by ESR in single crystals of AgNO3 x irradiated at 77°K and the principal values and corresponding principal axes of the g tensors and hyperfine tensors have been determined.
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