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Evaluation of interaction coefficient in Al-Cu-H alloy

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TLDR
In this paper, the interaction coefficient of Cu addition on the hydrogen activity for the Al-Cu-H system has been evaluated based on hydrogen solubility values in pure aluminum and in Al-cu alloy measured at different Cu concentrations by means of Sieverts' apparatus.
Abstract
The theory for interaction coefficient of alloying additions on hydrogen activity in Al alloys has been generally discussed. In particular, the interaction coefficient of Cu addition on the hydrogen activity for the Al-Cu-H system has been evaluated based on hydrogen solubility values in pure aluminum and in Al-Cu alloy measured at different Cu concentrations by means of Sieverts’ apparatus. The Cu addition was found to reduce the hydrogen solubility, and its effect on hydrogen solubility was evaluated by the interaction coefficient γ H Cu , which is a function of Cu-addition concentration and melt temperature. The evaluated interaction coefficient was converted into an alloy correction factor CF(A) and a temperature correction factor CF(T), which are employed in industrial hydrogen measurement techniques such as TELEGAS and ALSCAN.

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Citations
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Journal ArticleDOI

Modeling the Hydrogen Solubility in Liquid Aluminum Alloys

TL;DR: In this paper, the authors used the modified quasichemical model with the pair approximation (MQMPA) to estimate the thermodynamic properties of the multicomponent liquid solution from the liquid model parameters of lower order subsystems.
Journal ArticleDOI

Relationship between the Cu content and thermal properties of Al–Cu alloys for latent heat energy storage

TL;DR: In this paper, the effects of the Cu content on the phase change temperature, mass latent heat (LHM), LHV, supercooling degree and microstructure of Al-Cu alloys were first studied by means of power-compensated differential scanning calorimetry, density, composition analysis and metallographic analysis.
DissertationDOI

Evolution of Metal Foams during Solidification

M. Mukherjee
TL;DR: In this paper, the evolution of metal foams during solidification (cooling) was studied in-situ by means of X-ray radioscopy, where foam expansion was quantified by analysing the radioscopic image sequence.
Journal ArticleDOI

A Novel Characterization Technique to Determine Pore Susceptibility of Alloying Elements in Aluminum Alloys

TL;DR: In this paper, the effect of ternary alloying element additions such as copper, magnesium, manganese, zinc, and nickel on pore formation in cast Al-12.6-wt pct Si eutectic alloy by employing a novel pore characterization technique is reported.

Design and Analysis of a Process for Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides

TL;DR: The Transmutation Research Program (TRP) requires the incorporation of non-fertile actinides into the fuel matrix for the transmuter blanket as mentioned in this paper, which is an outstanding candidate for a transmutation fuel due to excellent irradiation performance and ease of fabrication.
References
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Journal ArticleDOI

Solubility of hydrogen in liquid aluminium

TL;DR: In this paper, the solubility of hydrogen in liquid pure aluminium was determined for temperatures from 943 to 1123 K and pressures from 67 to 113 kPa (0·66 to 1·12 atm), using an appropriate version of the Sieverts' method.
Journal ArticleDOI

The solubility of hydrogen in liquid binary Al-Li alloys

TL;DR: In this paper, the solubility of liquid binary aluminum alloys with 1, 2, and 3 wt pct lithium was determined for the temperature range of 913 to 1073 K and pressure 5.3 × 104 to 10.7 × 104 Pa, using an appropriate version of Sieverts' method.
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