Journal ArticleDOI
Evidence for photodisproportionation of d1-d1 dimers [(Mo{S2CN(CH2Ph)2}2)2O] (M = molybdenum, tungsten) containing linear oxobridges and for oxygen atom transfer from [WO2{S2CN(CH2Ph)2}2] to triethylphosphine
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This article is published in Inorganic Chemistry.The article was published on 1990-10-01. It has received 24 citations till now. The article focuses on the topics: Molybdenum & Tungsten.read more
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Book ChapterDOI
Bioinorganic chemistry of pterin-containing molybdenum and tungsten enzymes
John H. Enemark,Charles G. Young +1 more
TL;DR: The unexpected discovery that several hyperthermophilic organisms possess pterin-containing tungsten enzymes promises to stimulate the development of oxo-thio-tungsten chemistry.
Journal ArticleDOI
A thermodynamic scale for oxygen atom transfer reactions.
Richard H. Holm,James P. Donahue +1 more
Journal ArticleDOI
Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and -tungsten Complexes
TL;DR: In this paper, the relative rates of oxygen atom (oxo) transfer to substrate in second-order reactions [MO2(mnt)2]2- + (RO)3-nR‘nP → [MO 2[mnt]2]-2]-3nR'nPO in DMF solution (M = Mo, W; n = 0, R = Me, R‘ = Ph, n = 1, R= Et, R' = Me).
Journal ArticleDOI
cis-Dioxo-tungsten(VI) and -molybdenum(VI) complexes with N2O2 tetradentate ligands: synthesis, structure, electrochemistry and oxo-transfer properties
TL;DR: In this paper, a single crystal X-ray analysis revealed that the metal centre exhibits distorted octahedral co-ordination with cis-dioxo ligands and showed that these high-valent oxo complexes are active toward oxygen atom transfer reactions and can catalyse the oxidation of benzoin with dmso.
Journal ArticleDOI
Olefin Epoxidation by H2O2/MeCN Catalysed by Cyclopentadienyloxidotungsten(VI) and Molybdenum(VI) Complexes: Experiments and Computations
Chiara Dinoi,Chiara Dinoi,Marco Ciclosi,Eric Manoury,Laurent Maron,Laurent Maron,Laurent Maron,Lionel Perrin,Lionel Perrin,Rinaldo Poli,Rinaldo Poli +10 more
TL;DR: The epoxidation of ethylene as a model olefin, catalysed by the [Cp*MO(2)Cl] systems, has been investigated by DFT calculations with the use of the conductor-like polarisable continuum model (CPCM) and reproduces well the higher catalytic activity of the W species.