Journal ArticleDOI
Excess molar volumes of {an n-alkanol (methanol, ethanol, n-propanol, or n-butanol) or an n-alkane (n-hexane, n-heptane, or n-octane) + 1,2-dichloroethane} at 298.15 K
S.K. Chaudhari,S.S. Katti +1 more
TLDR
In this article, a continuous dilution dilatometer was used to measure the excess molar volumes of an n-alkanol (C 1 to C 4 ) or an n -alkane (C 6 to C 8 ) + 1,2-dichloroethane.About:
This article is published in The Journal of Chemical Thermodynamics.The article was published on 1989-06-01. It has received 4 citations till now. The article focuses on the topics: Heptane & Molar volume.read more
Citations
More filters
Journal ArticleDOI
Analysis of the intramolecular proximity effect on dichloroalkane + alkane mixtures using Nitta-Chao model
TL;DR: In this paper, the structure-dependent interaction energetic coefficients for the Nitta-Chao model were presented for a first time and compared with the predictions of DISQUAC and UNIFAC (version of Larsen et al.).
Journal ArticleDOI
Temperature and pressure dependence of the volumetric properties of binary liquid mixtures containing 1-propanol and dihaloalkanes
TL;DR: In this article, the densities of 1-propanol, + dibromomethane, or + bromochloromethanes were measured at 288.15, 298.15 and 308.15 K and pressures up to 2'×'107'Pa for the same mixtures.
Journal ArticleDOI
Densities and Excess Molar Volumes for the Binary and Ternary Systems of (1,4-Dioxane, 1-Propanol or 2-Propanol, and 1,2-Dichloroethane) at T = (288.15 to 318.15) K. Experimental Measurements and Prigogine–Flory–Patterson Modeling
TL;DR: In this article, the Redlich-Kister equation was used to measure the densities, ρ, and molar excess volumes for binary and ternary systems of (1,4-dioxane, 1-propanol or 2-Propanol, and 1,2-dichloroethane) over the whole composition range, at T = [288.15, 298.15] K, and atmospheric pressure.
Journal ArticleDOI
Quantitative accuracy in the gas chromatographic analysis of solvent mixtures
Johan Pettersson,Johan Roeraade +1 more
TL;DR: A simple procedure where calibration curves based on mass concentration are utilized and the densities of calibration mixtures of known compositions are determined with a density meter, in order to provide for correction factors caused by volume contractions.
References
More filters
Journal ArticleDOI
Excess volumes for n-alkanols + n-alkanes I. Binary mixtures of methanol, ethanol, n-propanol, and n-butanol + n-heptane
TL;DR: In this article, the excess volumes measured at 298.15 K in a successive-dilution dilatometer are reported for binary mixtures of the n-alkanols C1 to C4 + n-heptane.
Journal ArticleDOI
An improved dilution dilatometer for measurements of excess volumes
M.K Kumaran,M.L McGlashan +1 more
TL;DR: In this paper, a tilting dilution dilatometer is described, which is easier to calibrate and easier to load and operate than previous dilatometers, and has two advantages: no liquid passes through a greased tap and no tap is opened or closed throughout a series of dilution measurements.
Journal ArticleDOI
Excess volumes for alcohols + non-polar solvents I. Ethanol + cyclohexane, + n-hexane, + benzene, + carbon tetrachloride, + cyclopentane, and + p-xylene
K.N. Marsh,Carol Burfitt +1 more
TL;DR: In this paper, a dilution dilatometer for determining excess volumes at high dilutions of ethanol in the range x (C 2 H 5 OH) ≈ 1 × 10 −3 to ≈ 8 × 10−2, is described.
Journal ArticleDOI
HmE and VmE of some (1-chlorobutane + alkanol or cyclohexanol) mixtures
TL;DR: In this article, the authors measured excess enthalpies and excess molar volumes of (1-chlorobutane + an alkanol or cyclohexanol) at 298.15 and 308.15 K, respectively, and explained the results in terms of interactions involving the chlorine atom.
Journal ArticleDOI
Excess volumes of an alcohol + 1,2-dichloroethane
Nettem V. Choudary,P. R. Naidu +1 more
TL;DR: In this article, the excess volumes for binary mixtures of 1,2-dichloroethane with n-propanol, n-butanol, N-pentanol, nhexanol, and n-heptanol have been determined at 303.15