Journal ArticleDOI
Four bridging bis chelate ligands with very low lying .pi.* orbitals. MO perturbation calculations, electrochemistry, and spectroscopy of mononuclear and binuclear group 6 metal tetracarbonyl complexes
Wolfgang Kaim,Stephan Kohlmann +1 more
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This article is published in Inorganic Chemistry.The article was published on 1987-01-01. It has received 145 citations till now.read more
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Exchange coupling and magnetic blocking in bipyrimidyl radical-bridged dilanthanide complexes.
TL;DR: The synthesis and magnetic properties of three new bipyrimidyl radical-bridged dilanthanide complexes, [(Cp*(2)Ln)(2)(μ-bpym(•))](+) (Ln = Gd, Tb, Dy), are reported.
Journal ArticleDOI
Aromatic nitrogen heterocycles as bridging ligands; a survey
TL;DR: In this paper, a serie de coordinats bidentes et tridentes, heterocycliques azotes are discussed, together with a discussion of the relation between them.
Journal ArticleDOI
N,N′-Chelating biheteroaromatic ligands; a survey
TL;DR: Etude de coordinats organiques heterocycliques azotes ou possedant des atomes de soufre (ou oxygene) and d'azote as mentioned in this paper.
Journal ArticleDOI
The coordination chemistry of 1,2,4,5-tetrazines
TL;DR: 1,2,4,5-Tetrazine and its 3,6-disubstituted derivatives exhibit a particular coordination chemistry, characterized by electron and charge transfer phenomena and by the ability of these heteroatom-rich ligands to bridge metal centers in various ways as mentioned in this paper.
Journal ArticleDOI
Complexes with 2,2â²-azobispyridine and related 'S-frame' bridging ligands containing the azo function
TL;DR: Bridging ligands involving the azo group as coordinating π acceptor function can yield dinuclear complexes with unusual electronic and structural features as discussed by the authors, including several easily accessible oxidation states, longwavelength charge-transfer absorptions, relatively small metal-metal distances, various forms of isomerism, and the stability of radical intermediates and/or mixed-valent states.
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Energy level tailoring in ruthenium(II) polyazine complexes based on calculated and experimental ligand properties
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Coordination characteristics of four isomeric .alpha.-diimine ligands. .pi. Molecular orbital perturbation calculations for the bidiazines and their correlation with the properties of group 6 metal carbonyl complexes
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