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Journal ArticleDOI

Glass transition temperature and sequential structure of equimolar copolymers

Masaaki Hirooka, +1 more
- 01 Jan 1974 - 
- Vol. 12, Iss: 1, pp 31-37
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This article is published in Journal of Polymer Science: Polymer Letters Edition.The article was published on 1974-01-01. It has received 42 citations till now. The article focuses on the topics: Glass transition & Copolymer.

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Synthesis of Sequence-Specific Vinyl Copolymers by Regioselective ROMP of Multiply Substituted Cyclooctenes

TL;DR: In this article, a variety of multisubstituted cyclooctenes were prepared and employed as monomers for ring-opening metathesis polymerization using the Grubbs second or third generation catalysts.
Journal ArticleDOI

Sequence Distribution-Glass Transition Effects

TL;DR: In this article, the effect of copolymerization on the polymer glass transition (Tg) is investigated and the effect on Tg properties has not yet been fully understood by the authors.
Journal ArticleDOI

A Comprehensive Simulator/Database Package for Reviewing Free-Radical Homopolymerizations

TL;DR: This work simulates free-radical homopolymerizations under restricted polymerization conditions with real-world examples of several different types of monomer systems.
Journal ArticleDOI

Glass transition temperature of allyl methacrylate-n-butyl acrylate gradient copolymers in dependence on chemical composition and molecular weight

TL;DR: In this article, the glass transition temperatures of spontaneous gradient copolymers of P(AMA-co-BA) were measured using differential scanning calorimetry, where the expected increase in Tg with the augment of the monomer conversion is compensated by the enrichment of BA as the polymerization reaction progresses.
Journal ArticleDOI

Glass transition temperatures of butyl acrylate–methyl methacrylate copolymers

TL;DR: In this article, the glass transition temperatures Tg of butyl acrylate-methyl methacrylate copolymers obtained by free radical polymerization in 3 and 5 mol/L benzene solution have been measured using differential scanning calorimetry (DSC) and the values have been correlated using Johnston's equation with inter-intramolecular copolymer structure.