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Journal ArticleDOI

Hydroboration. XXVII. The hydroboration of 1-butenyl and related vinyl derivatives containing representative substituents. An unusually powerful directive influence of the ethoxy substituent

Herbert C. Brown, +1 more
- 01 May 1968 - 
- Vol. 90, Iss: 11, pp 2915-2927
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This article is published in Journal of the American Chemical Society.The article was published on 1968-05-01. It has received 108 citations till now. The article focuses on the topics: Hydroboration & Substituent.

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Book ChapterDOI

Boranes in Organic Chemistry

Herbert C. Brown
- 01 Jan 1972 - 
TL;DR: In this article, the authors discuss boranes in organic chemistry, diborane as a reducing agent, volatile compounds of uranium, the alkali metal hydride approach to borane, and borohydrides.
Journal ArticleDOI

A study of hydroboration of alkenes and alkynes with pinacolborane catalyzed by transition metals

Schubert Pereira, +1 more
- 06 May 1996 - 
TL;DR: Pinacolborane (PBH) is an excellent stoichiometric hydroboration reagent for alkenes and alkynes in the presence of catalytic amounts of transition metals as mentioned in this paper.
Journal ArticleDOI

Organoborane-carbon monoxide reactions. Synthesis of carbon structures

Herbert C. Brown
- 01 Mar 1969 - 
Journal ArticleDOI

Regioselective Borylation of the C–H Bonds in Alkylamines and Alkyl Ethers. Observation and Origin of High Reactivity of Primary C–H Bonds Beta to Nitrogen and Oxygen

Qian Li, +2 more
- 05 Jun 2014 - 
TL;DR: Experimental studies and computational results show that C-H bond cleavage is the rate-determining step of the current borylation reactions.
Journal ArticleDOI

X-ray crystal structure of a chiral oxazaborolidine catalyst for enantioselective carbonyl reduction

E. J. Corey, +2 more
- 09 Jun 1992 - 
Related Papers (5)

Hydroboration. XXVI. The hydroboration of 2-butenyl (crotyl) and related derivatives containing representative substituents. Control of the elimination reaction of .beta.-substituted organoboranes

Herbert C. Brown, +1 more
- 01 May 1968 - 

Cyclic hydroboration of 1,5-cyclooctadiene. A simple synthesis of 9-borabicyclo[3.3.1]nonane, an unusually stable dialkylborane

Evord F. Knights, +1 more
- 01 Sep 1968 - 

Hydroboration. VII. Directive Effects in the Hydroboration of Olefins

Herbert C. Brown, +1 more
- 01 Sep 1960 - 

Hydroboration. IX. The Hydroboration of Cyclic and Bicyclic Olefins—Stereochemistry of the Hydroboration Reaction

Herbert C. Brown, +1 more
- 01 Jun 1961 - 

Hydroboration. XXXVI. Direct route to 9-borabicyclo[3.3.1]nonane via the cyclic hydroboration of 1,5-cyclooctadiene. 9-Borabicyclo[3.3.1]nonane as a uniquely selective reagent for the hydroboration of olefins

Herbert C. Brown, +2 more
- 01 Dec 1974 -