Hydroformylation with a rhodium/bulky phosphite modified catalyst. A comparison of the catlyst behaviour for oct-1-ene, cyclohexene and styrene
TLDR
In this paper, the rhodium-catalyzed hydroformylation of oct-1-ene, cyclohexene, and styrene has been studied using Rh(C0)Acac as the catalyst precursor and tris(2-tert-butyl-4-methylphenyl) phosphite as the ligand.About:
This article is published in Organometallics.The article was published on 1995-01-01 and is currently open access. It has received 241 citations till now. The article focuses on the topics: Cyclohexene & Hydroformylation.read more
Citations
More filters
Journal ArticleDOI
Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
TL;DR: The history of “ligand effects” in catalysis, a range of reactions for which a notable effect has been observed, and some of the established examples of bite angle effects involve diphosphine ligands.
Journal ArticleDOI
Progress in hydroformylation and carbonylation
TL;DR: The last 15 years of hydroformylation and carbonylation chemistry are reviewed in this article, including technical and commercial aspects, and the authors present a review of the most relevant papers.
Journal ArticleDOI
Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine−Phosphite Ligands
Kyoko Nozaki,Nozomu Sakai,Tetsuo Nanno,Takanori Higashijima,Satoshi Mano,and Toshihide Horiuchi,Hidemasa Takaya +6 more
TL;DR: A chiral phosphine−phosphite ligand, (R)-2-(diphenylphosphino)-1,1‘-binaphthalen-2,2
Journal ArticleDOI
Origin of the Bite Angle Effect in Rhodium Diphosphine Catalyzed Hydroformylation.
L.A. van der Veen,H. Keeven,G.C. Schoemaker,Joost N. H. Reek,P.C.J. Kamer,P.W.N.M. van Leeuwen,Martin Lutz,A. L. Spek +7 more
TL;DR: In this article, the bite angle effect on the rhodium diphosphine catalyzed hydroformylation was investigated in detail, and a series of xantphos-type ligands with natural bite angles ranging from 102° to 121° was synthesized, and the effect of the natural bite angle on coordination chemistry and catalytic performance was studied.
Journal ArticleDOI
New processes for the selective production of 1-octene
TL;DR: A review of 1-hexene and 1-octene production based on homogeneous catalysts can be found in this paper, where it is shown that 1hexene constitutes only a minor part of the total yield.