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Kinetic Model for Wet Oxidation of Organic Compounds in Subcritical and Supercritical Water

L. Li
- 01 Jan 1993 - 
- Vol. 514, pp 305-313
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This article is published in Acs Symposium Series.The article was published on 1993-01-01 and is currently open access. It has received 26 citations till now. The article focuses on the topics: Supercritical fluid & Supercritical water oxidation.

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Physicochemical Treatment of Hazardous Wastes

TL;DR: In this paper, the authors examined the treatability of hazardous wastes by different physicochemical treatment processes according to the Quantitative Structure and Activity Relationship (QSAR) between kinetic rate constants and molecular descriptors.
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Catalytic supercritical water oxidation: phenol conversion and product selectivity.

TL;DR: The values of the rate constants were higher in the catalytic experiments compared with the homogeneous runs, further indicating that the addition of the heterogeneous catalyst promoted the oxidation pathways at the expense of the oligimerization pathway.
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Problems in Supercritical Water Oxidation Process and Proposed Solutions

TL;DR: In this article, the main technical solutions studied by numerous authors to avoid the drawbacks of the Supercritical Water Oxidation (SCWO) process for industrial wastewaters are reviewed.
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Supercritical water oxidation for the destruction of municipal excess sludge and alcohol distillery wastewater of molasses

TL;DR: In this article, the supercritical water oxidation was applied to municipal excess sludge and alcohol distillery wastewater of molasses in a batch reactor or a flow reactor with hydrogen peroxide as an oxidant in the temperature range 473-873 K. The liquid phase products were colorless and odorless.
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Supercritical water oxidation with hydrothermal flame as internal heat source: Efficient and clean energy production from waste

TL;DR: In this paper, the state of the art of supercritical water oxidation (SCWO) has been reviewed, focusing on energy production, and a good comprehension of thermal and transport properties of mixtures at supercritical state, as well as oxidation kinetics under that condition are essential data that must be further investigated in order to find energetically efficient processes.
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