Journal ArticleDOI
Kinetics of the isomerization of quadricyclane to norbornadiene promoted by tin(II) chloride and palladium(II) chloride
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This article is published in ChemInform.The article was published on 1984-12-25. It has received 4 citations till now. The article focuses on the topics: Norbornadiene & Tin(II) chloride.read more
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Journal ArticleDOI
Enthalpy of isomerization of quadricyclane to norbornadiene
Xu-Wu An,Yin-de Xie +1 more
TL;DR: In this paper, the enthalpy of isomerization of quadricyclane (QC) to norbornadiene (NBD) in a benzene solution has been measured at room temperature in the presence of HgBr 2.
Book ChapterDOI
Molecular Solar-Thermal Energy Storage: Molecular Design and Functional Devices
TL;DR: In molecular solar-thermal energy storage (MOST), solar energy is stored in chemical bonds; this is achieved using compounds undergoing photoinduced isomerisation to metastable isomers.
Journal ArticleDOI
Effect of Aryl Substituents on 2-Aryl-1,4,5,6,7,7-hexachloronorbornadiene–Quadricyclane Reversible Isomerization
TL;DR: In this paper, the effect of aryl substituents on the thermal reversion was investigated and it was shown that spin delocalization and polar effect equally contribute to the stabilization of the transition state.
Multi-Configurational Investigation of Thermolytic Pathways of Highly Strained Ring Systems
TL;DR: In this paper, the potential energy surfaces (PESs) for σ bond breaking and π bond rotation in high energy structures were investigated, and it was shown that resonance and or electronegativity would affect the allowed or disallowed nature of the activation barriers in these systems.
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Regio- and stereoselective formation and isomerization of 1,3-cyclohexadienes catalyzed by titanium aryloxide compounds
Gary J. Balaich,Ian P. Rothwell +1 more