Journal ArticleDOI
Linear sweep voltammetry. Effect of uncompensated cell resistance and double layer charging on polarization curves
J.C. Imbeaux,Jean-Michel Savéant +1 more
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TLDR
In this article, the effect of the ohmic drop in the uncompensated cell resistance on the polarization curves has been analyzed and a simple correction procedure is suggested for small values of the Ohmic drop.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1970-12-01. It has received 95 citations till now. The article focuses on the topics: Linear sweep voltammetry & Ohmic contact.read more
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Digital Simulation in Electrochemistry
TL;DR: In this paper, the Explicit Method and the Explicit Methods of the Implicit Methods are discussed, as well as several other methods, such as adorption and convection of two-dimensional systems.
Journal ArticleDOI
Convolution potential sweep voltammetry
J.C. Imbeaux,Jean-Michel Savéant +1 more
TL;DR: In this paper, a convolution potential sweep voltammetry (CPSV) method is proposed for processing the data obtained by linear sweep voltageammetry, which consists in calculating directly from the experimental data the convolution integral of the current time function with the function t − 1/2.
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Ultramicroelectrodes in Electrochemistry
TL;DR: In this paper, the changes in mass transport conditions bring about extremely high current densities at ultramicroelectrodes, whereas the currents themselves become very small, which allows for many electroanalytical applications that are not possible with conventional electrodes, especially experiments in solutions with very low electrolyte concentrations.
References
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Journal ArticleDOI
Some Examples of the Numerical Solution of Nonlinear Integral Equations
Journal ArticleDOI
Electrodimerization: I. One-electron irreversible dimerization. Diagnostic criteria and rate determination procedures for voltammetric studies
Journal ArticleDOI
Distortion of linear-sweep polarograms by ohmic drop
W.T. De Vries,E. C. van Dalen +1 more
TL;DR: In this paper, an exact computation of reversible linear-sweep polarograms at a plane electrode distorted by ohmic drop is presented, and it is deduced that for quantitative studies of electrode processes, the use of a mercury-drop electrode (or other micro-electrodes of similar geometry) in conjunction with linear sweep voltammetry should be avoided.
Journal ArticleDOI
Potential sweep voltammetry with uncompensated ohmic potential drop. Irreversible charge transfer
TL;DR: In this paper, the potential sweep voltammetric curves for a totally irreversible electrode process with uncompensated ohmic drop, when mass transfer takes place by semi-infinite linear diffusion, have been calculated.
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