Journal ArticleDOI
Mechanism and regioisomeric control in palladium(II)-mediated cycloalkenylations. A novel total synthesis of (.+-.)-quadrone
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This article is published in Journal of the American Chemical Society.The article was published on 1982-10-01. It has received 80 citations till now. The article focuses on the topics: Total synthesis & Palladium.read more
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Palladium-katalysierte Kupplungsreaktionen organischer Elektrophile mit Organozinn-Verbindungen
TL;DR: Palladium-katalysierte Kupplungsreaktionen von Organozinn-Verbindungen with unterschiedlichsten organischen Elektrophilen sind eine relativ neue Methode zur Knupfung von Kohlenstoff-Kohlenstoffs-Bindungen.
Journal ArticleDOI
Palladium-catalyzed cycloisomerizations of enynes and related reactions
Journal ArticleDOI
Synthesis of Polyquinane Natural Products: An Update.
Journal ArticleDOI
Selective Synthesis by Use of Lewis Acids in the Presence of Organocopper and Related Reagents. New Synthetic Methods (61)
TL;DR: In this paper, it was shown that the two species cannot coexist and undergo transmetalation reactions at low temperature, but they exhibit new and unique reactivities and selectivities: in conjugate additions, e.g., not only activation but also high regio-, stereo-, and chemo-selectivity as well as very high asymmetric induction.
Book ChapterDOI
3.3 – Nucleophiles with Allyl–Metal Complexes
TL;DR: In this paper, the focus of this chapter is on the selectivities, namely chemo-, diastereo-, regio- and enantio-selectivity, that are exhibited by π-allylpalladium chemistry.