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Molecular orbital calculations for complexes of heavier transition elements. II. Hexachloro complexes of tetravalent rhenium, osmium, iridium, and platinum

F. Albert Cotton, +1 more
- 01 Feb 1967 - 
- Vol. 6, Iss: 2, pp 376-379
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This article is published in Inorganic Chemistry.The article was published on 1967-02-01. It has received 40 citations till now. The article focuses on the topics: Osmium & Rhenium.

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Probing Free Multiply Charged Anions Using Photodetachment Photoelectron Spectroscopy

TL;DR: In this article, a new experimental technique, using photodetachment photoelectron spectroscopy, electrospray, and ion-trap mass spectrometry, has been developed in the author's laboratory to probe multiply charged anions in the gas phase.
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Photodetachment of free hexahalogenometallate doubly charged anions in the gas phase: [ML6]2−, (M=Re, Os, Ir, Pt; L=Cl and Br)

TL;DR: In this paper, the first observation and photodetachment photoelectron spectroscopic study of a series of hexahalogenometallates dianions MCl62− (M=Re, Os, Ir, and Pt) in the gas phase was reported.
Journal ArticleDOI

Optical Spectra of Os4+ in Single Cubic Crystals at 4.2°K

TL;DR: In this paper, the optical spectra of Os4+ (5d4) in single cubic crystals of K2PtCl6, Cs2ZrCl6 and Rb2ZRCl6 at 4.2°K has been studied.
Journal ArticleDOI

Molecular orbital investigation of chemisorption. I. Hydrogen on tungsten (100) surface

TL;DR: In this article, the relative bonding energies of nitrogen chemisorbed at three symmetric sites on a W(100) surface, represented by finite arrays of tungsten atoms, were obtained by means of the extended Huckel molecular orbital theory (EHMO).
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