Journal ArticleDOI
Molecular theory of the Trommsdorff effect
Thomas J. Tulig,Matthew Tirrell +1 more
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This article is published in Macromolecules.The article was published on 1981-09-01. It has received 194 citations till now.read more
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Book ChapterDOI
Network formation by chain crosslinking photopolymerization and some applications in electronics
TL;DR: In this paper, the formation of densely crosslinked networks by chain crosslinking photopolymerization is discussed in relation to selected applications in the electronics industry, which make use of the high speed and the latitude to meet other requirements by variation of the chemical structure of the monomers.
Journal ArticleDOI
Toward an enhanced understanding and implementation of photopolymerization reactions
TL;DR: In this article, the authors have modeled and experimentally validated the complex spatially dependent polymerization kinetics and network heterogeneity, and implemented these systems for applications improvement or development in lithography, microdevice fabrication, biomaterials, biodetection, dental materials, and surface coatings.
Journal ArticleDOI
Free Radical Polymerization of n-Butyl Methacrylate in Ionic Liquids
TL;DR: In this article, ionic liquids based on imidazolium, pyridinium, and alkylammonium salts were investigated as solvents in free radical polymerization of the model monomer n-butyl methacrylate.
Journal ArticleDOI
Kinetics of diffusion‐controlled processes in dense polymer systems. II. Effects of entanglements
TL;DR: In this article, the authors analyzed the diffusion-controlled reaction between two partners A and B attached to two long, flexible chains in a homodisperse polymer melt and found a time-independent rate constant k(t)∼t−3/8 (independent of N).
Journal ArticleDOI
Bimolecular radical termination: New perspectives and insights
TL;DR: In this paper, the authors investigated the effect of polymer matrix architecture on the termination of linear polyMA radicals and compared this to polystyrene, polymethyl methacrylate, and polyvinyl acetate systems.