Journal ArticleDOI
Mono‐ and Bi‐nuclear Gold(I), Gold(II), and Gold(III) Perhalogenoaryl Complexes with the Ligand Bis(diphenylphosphino)amine.
TLDR
In this article, bis(diphenylphosphino)amine was added to neutral or cationic gold(I) and gold(III) complexes containing weakly coordinated neutral ligands.Abstract:
Addition of bis(diphenylphosphino)amine to neutral or cationic gold(I) and gold(III) complexes containing weakly coordinated neutral ligands leads to the formation of the complexes (II), (IV), (VI), and (IX).read more
Citations
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Journal ArticleDOI
Exceptionally fast carbon–carbon bond reductive elimination from gold( III )
TL;DR: It is shown that oxidation of a series of mono- and bimetallic Au(I) aryl complexes at low temperature generates observable Au(III) and Au(II) intermediates and that aRYl-aryl bond reductive elimination from these oxidized species is not only among the fastest observed for any transition metal, but is also mechanistically distinct from previously studied alkyl-alkyl and ary lalkyl reductive eliminations from Au( III.
References
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Journal ArticleDOI
Mono- and bi-nuclear gold(I), gold(II), and gold(III) perhalogenoaryl complexes with the ligand bis(diphenylphosphino)amine. Crystal and molecular structure of µ-[bis(diphenylphosphino)amine]-dichlorobis(pentafluorophenyl)digold(II)
Rafael Usón,Antonio Laguna,Mariano Laguna,M. Nieves Fraile,Peter G. Jones,George M. Sheldrick +5 more
TL;DR: In this article, the structure of the complex (C6F5)ClAu(dppa)AuCl(C6Fs5) has been determined by single-crystal X-ray diffraction: space group C2/c, a= 18.009(3), b= 17.033(2), c=18.420(3)
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