Journal ArticleDOI
Nernst-controlled Currents in Hanging-drop Polarography
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This article is published in Journal of the American Chemical Society.The article was published on 1957-12-01. It has received 104 citations till now. The article focuses on the topics: Nernst equation & Drop (liquid).read more
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Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
R. S. Nicholson,Irving. Shain +1 more
TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
Journal ArticleDOI
Convolution potential sweep voltammetry
J.C. Imbeaux,Jean-Michel Savéant +1 more
TL;DR: In this paper, a convolution potential sweep voltammetry (CPSV) method is proposed for processing the data obtained by linear sweep voltageammetry, which consists in calculating directly from the experimental data the convolution integral of the current time function with the function t − 1/2.
Journal ArticleDOI
Ultramicroelectrodes in Electrochemistry
TL;DR: In this paper, the changes in mass transport conditions bring about extremely high current densities at ultramicroelectrodes, whereas the currents themselves become very small, which allows for many electroanalytical applications that are not possible with conventional electrodes, especially experiments in solutions with very low electrolyte concentrations.
Journal ArticleDOI
Fabrication and Use of Nanometer-Sized Electrodes in Electrochemistry
TL;DR: Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies that have enabled the measurement of electron-transfer rate constants, khet, that are two orders of magnitude faster than khet values accessible with any other electrochemical method.
Related Papers (5)
Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
R. S. Nicholson,Irving. Shain +1 more