Journal ArticleDOI
Non-linear resonances in quadrupole mass spectrometers due to imperfect fields
P.H. Dawson,N.R. Whetten +1 more
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TLDR
In this article, a theory of non-linear resonances is applied to the quadrupole mass filter and to the monopole mass spectrometer to determine the extent of peak splitting for various amounts of third and fourth order spacial distortion.About:
This article is published in International Journal of Mass Spectrometry and Ion Physics.The article was published on 1969-09-01. It has received 59 citations till now. The article focuses on the topics: Quadrupole mass analyzer & Quadrupole ion trap.read more
Citations
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Journal ArticleDOI
Linear ion traps in mass spectrometry.
TL;DR: Potentials and ion motion in linear multipole fields and methods of ion trapping, cooling, excitation, and isolation are described, and a description of various mass discrimination effects that have been reported with linear ion traps are reported.
Book
Quadrupole ion trap mass spectrometry
TL;DR: The quadrupole ion trap mass spectrometer (QITMS) as discussed by the authors is an example of a mass-selective mass analyzer that can be used as a single-stage mass analyter.
Journal ArticleDOI
Linear quadrupoles in mass spectrometry.
TL;DR: Extensions of quadrupole mass filters to higher masses, scanning with frequency sweeps of the quadrupoles waveform, operation in higher stability regions, and operation with rectangular or other periodic waveforms are discussed.
Journal ArticleDOI
Quadrupole mass analyzers: performance, design and some recent applications
Book ChapterDOI
Quadrupole ion trap mass spectrometry.
Jae C. Schwartz,Ian Jardine +1 more
TL;DR: The ability of the QITMS to interface to key separations systems such as HPLC and HPCE through the critical ionization techniques of ESI and MALDI, coupled with the high mass range, high mass resolution, high sensitivity, high-efficiency CID, and MS capabilities of this device, will provide an astonishing array of cost-effective capabilities for the qualitative and quantitative analysis of biological macromolecules.
References
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Journal ArticleDOI
Monopole Spectrometer, a New Electric Field Mass Spectrometer
TL;DR: The monopole spectrometer as mentioned in this paper uses an electric field between a two-electrode configuration for analyzing ions of different e/m. The properties of the instrument are derived from an approximate equation for the ion motion.
Journal ArticleDOI
Ion storage in three-dimensional, rotationally symmetric, quadrupole fields. ii. a sensitive mass spectrometer.
P. H. Dawson,N. R. Whetten +1 more
TL;DR: In this paper, a mass spectrometer was constructed in which ions were trapped in a three-dimensional, rotationally symmetric, quadrupole field and then periodically drawn out of the trapping field into an electron multiplier.
Journal ArticleDOI
Computation of ion trajectories in the monopole mass spectrometer by numerical integration of Mathieu's equation
Abstract: A high speed digital computer used with an off-line curve plotter enabled ion trajectories to be readily obtained in terms of the initial conditions and the parameters appearing in the differential...
Journal ArticleDOI
The Monopole Mass Spectrometer
P. H. Dawson,N. R. Whetten +1 more
TL;DR: In this paper, the trajectories were computed by numerical integration of the Mathieu equations of motion, and the influence of entrance and exit slit dimensions and rod-Vee block spacing was determined.
Journal ArticleDOI
Some Properties of the Monopole Mass Spectrometer
P. H. Dawson,N. R. Whetten +1 more
TL;DR: In this paper, the authors derived peak shapes for ions spending 20 rf cycles in the field, for various entrance/exit slit ratios, with ion injection parallel to the instrument axis.
Related Papers (5)
Non-linear resonances in quadrupole mass spectrometers due to imperfect fields I. The quadrupole ion trap
P.H. Dawson,N.R. Whetten +1 more
The non-linear resonance ion trap. Part 2. A general theoretical analysis
Y. Wang,J. Franzen,K.P. Wanczek +2 more