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Journal ArticleDOI

Non-linear resonances in quadrupole mass spectrometers due to imperfect fields

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TLDR
In this article, a theory of non-linear resonances is applied to the quadrupole mass filter and to the monopole mass spectrometer to determine the extent of peak splitting for various amounts of third and fourth order spacial distortion.
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This article is published in International Journal of Mass Spectrometry and Ion Physics.The article was published on 1969-09-01. It has received 59 citations till now. The article focuses on the topics: Quadrupole mass analyzer & Quadrupole ion trap.

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Citations
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Journal ArticleDOI

Linear ion traps in mass spectrometry.

TL;DR: Potentials and ion motion in linear multipole fields and methods of ion trapping, cooling, excitation, and isolation are described, and a description of various mass discrimination effects that have been reported with linear ion traps are reported.
Book

Quadrupole ion trap mass spectrometry

TL;DR: The quadrupole ion trap mass spectrometer (QITMS) as discussed by the authors is an example of a mass-selective mass analyzer that can be used as a single-stage mass analyter.
Journal ArticleDOI

Linear quadrupoles in mass spectrometry.

TL;DR: Extensions of quadrupole mass filters to higher masses, scanning with frequency sweeps of the quadrupoles waveform, operation in higher stability regions, and operation with rectangular or other periodic waveforms are discussed.
Book ChapterDOI

Quadrupole ion trap mass spectrometry.

TL;DR: The ability of the QITMS to interface to key separations systems such as HPLC and HPCE through the critical ionization techniques of ESI and MALDI, coupled with the high mass range, high mass resolution, high sensitivity, high-efficiency CID, and MS capabilities of this device, will provide an astonishing array of cost-effective capabilities for the qualitative and quantitative analysis of biological macromolecules.
References
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Journal ArticleDOI

Monopole Spectrometer, a New Electric Field Mass Spectrometer

TL;DR: The monopole spectrometer as mentioned in this paper uses an electric field between a two-electrode configuration for analyzing ions of different e/m. The properties of the instrument are derived from an approximate equation for the ion motion.
Journal ArticleDOI

Ion storage in three-dimensional, rotationally symmetric, quadrupole fields. ii. a sensitive mass spectrometer.

TL;DR: In this paper, a mass spectrometer was constructed in which ions were trapped in a three-dimensional, rotationally symmetric, quadrupole field and then periodically drawn out of the trapping field into an electron multiplier.
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Computation of ion trajectories in the monopole mass spectrometer by numerical integration of Mathieu's equation

Abstract: A high speed digital computer used with an off-line curve plotter enabled ion trajectories to be readily obtained in terms of the initial conditions and the parameters appearing in the differential...
Journal ArticleDOI

The Monopole Mass Spectrometer

TL;DR: In this paper, the trajectories were computed by numerical integration of the Mathieu equations of motion, and the influence of entrance and exit slit dimensions and rod-Vee block spacing was determined.
Journal ArticleDOI

Some Properties of the Monopole Mass Spectrometer

TL;DR: In this paper, the authors derived peak shapes for ions spending 20 rf cycles in the field, for various entrance/exit slit ratios, with ion injection parallel to the instrument axis.