Journal ArticleDOI
Oxidation of furans. 2. Synthesis and biological properties of 6-hydroxy-2H-pyran-3(6H)-ones and derivatives
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This article is published in Journal of Medicinal Chemistry.The article was published on 1973-10-01. It has received 60 citations till now. The article focuses on the topics: Pyran.read more
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Journal ArticleDOI
Stereoselective total synthesis of methyl α-d- and α-l-glucopyranosides
Osman Achmatowicz,Roman Bielski +1 more
TL;DR: In this paper, the key intermediates, methyl alpha-L- and alpha-D-glucopyranosides, were obtained in seven steps from the ester without change of configuration of the asymmetric center, which became C-5 in the sugar molecule.
Journal ArticleDOI
Furans and singlet oxygen – why there is more to come from this powerful partnership
Tamsyn Montagnon,Dimitris Kalaitzakis,Myron Triantafyllakis,Manolis Stratakis,Georgios Vassilikogiannakis +4 more
TL;DR: The purpose of this article is to give a taste of just how powerful the union between furans and photochemically-generated singlet oxygen is proving to be as a synthetic tool and to suggest that this chemistry is only now really coming of age.
Book ChapterDOI
The Synthesis of Sugars from Non-Carbohydrate Substrates
TL;DR: In this paper, the synthesis of sugar-type compounds containing four or more carbon atoms, an aldehyde or a ketone group, and a minimum of two hydroxyl groups (or their equivalents, such as amino or thiol groups) with at least one of them being bound to a center of chirality is described.
Journal ArticleDOI
A new synthesis of 3-oxocyclopentenes
TL;DR: In this paper, a thermal electrocyclic reaction of a 4π electrons system was described for the synthesis of (±) allethrolone, and an application relative to the (±)-alletholone synthesis was reported.
Journal ArticleDOI
Catalytic Environmentally Friendly Protocol for Achmatowicz Rearrangement.
Zhilong Li,Rongbiao Tong +1 more
TL;DR: Mechanism-guided analysis enables a new catalytic method (Oxone/KBr) for AchR in excellent yield with K2SO4 as the only side product, which greatly facilitates the purification.