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Polarographic reduction of the azines
Kenneth B. Wiberg,Thomas Lewis +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1970-12-01. It has received 124 citations till now.read more
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Reductive Silylation Using a Bis-silylated Diaza-2,5-cyclohexadiene
TL;DR: Reductive silylation reactions show a strong solvent dependence where a polar solvent facilitates conversions, perhaps giving limited insight on the mechanism of this very attractive reductive process.
Journal ArticleDOI
Redox Potential Tuning of s-Tetrazine by Substitution of Electron-Withdrawing/Donating Groups for Organic Electrode Materials
TL;DR: In this paper, the redox potential of 3,6-diphenyl-1,2,4,5-tetrazine (DPT) was tuned by introducing various electron-donating/withdrawing groups (methoxy, t-butyl, H, F, and trifluoromethyl) into its two peripheral benzene rings for use as electrode material in a Li-ion cell.
Journal ArticleDOI
Stabilisierung biochemisch interessanter Zwischenstufen durch Metallkoordination: II. 5,8-Bis(trimethylsilyl)-5,8-dihydropteridin und seine Deaza-Derivate
TL;DR: Reductive trimethylsilylation of pteridine, of its 1-and 3-deaza derivatives 1,4,6- and 1, 4,5-triazanaphthalene, and of the 1,3-dideaza derivative quinoxaline yields the primary reduced forms of these heterocycles, which contain the 1 4-dihydro-1,4-diazine ring with 8 conjugated π-electrons as the only low molecular weight products as mentioned in this paper.
Journal ArticleDOI
Heteroaromatic Radicals, Part I: General Properties; Radicals with Group V Ring Heteroatoms
TL;DR: In this paper, the general properties of heteroaromatic radicals in terms of the distribution of spin are presented. And the chemistry of radicals containing solely Group V ring heteroatoms is also reviewed in the chapter.
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