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Journal ArticleDOI

Proton-transfer reactions in the cathodic reduction of bromohydrins in neutral aprotic media

TLDR
Polarographic and cyclic voltammetric studies of bromohydrins in acetonitrile showed a single diffusion-limited two-electron irreversible cathodic wave/peak followed by chemical transformations as discussed by the authors.
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This article is published in Journal of Electroanalytical Chemistry.The article was published on 1993-08-16. It has received 0 citations till now. The article focuses on the topics: Acetonitrile.

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Journal ArticleDOI

Selective Reduction of the CarbonBromine Bond in Bromo Epoxides

TL;DR: The controlledpotential electrolysis of various substituted bromo epoxides in acetonitrile at a mercury pool electrode led to selective reduction of the carbon-bromine bond affording the respective epoxide products in 80-90% yield.
Journal ArticleDOI

A selective cathodic reduction of β-chlorovinylimines in N,N′ dimethylformamide

TL;DR: The controlledpotential electrolyses of various substituted chlorovinylimines, viz., 4-chloro-3-(N-aryliminomethyl)-2H(1)-benzopyrans in dimethylformamide(DMF) solutions at mercury pool electrode yielded selectively the corresponding chlorine reduced products in moderately good yields.
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