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Journal ArticleDOI

Regio- and stereoselective .gamma. substitution of allylic alcohols with alkyllithium compounds by using N,N-methylphenylaminotributylphosphonium iodide. Anti stereochemistry of SN2' reaction

Yoshio Tanigawa, +3 more
- 01 Jul 1978 - 
- Vol. 100, Iss: 14, pp 4610-4612
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This article is published in Journal of the American Chemical Society.The article was published on 1978-07-01. It has received 32 citations till now. The article focuses on the topics: Allylic rearrangement & SN2 reaction.

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Journal ArticleDOI

Stereocontrol in the synthesis of acyclic systems: applications to natural product synthesis

Paul A. Bartlett
- 01 Jan 1980 - 
Journal ArticleDOI

Nucleophilic and organometallic displacement reactions of allylic compounds: stereo-and regiochemistry

Ronald M. Magid
- 01 Jan 1980 - 
TL;DR: In this paper, stereo and regiochemical aspects of three reaction types: the SN2' reaction (bimolecular nucleophilic substitution with allylic rearrangement); displacement reactions effected by organometallic reagents; the conversion of allylic alcohols into halides.
Journal ArticleDOI

Synthetic uses of the 1,3-dithiane grouping from 1977 to 1988

Philip C. Bulman Page, +2 more
- 01 Jan 1989 - 
Journal ArticleDOI

d-Orbital stereoelectronic control of the stereochemistry of SN2' displacements by organocuprate reagents

E. J. Corey, +1 more
- 01 Jan 1984 - 
TL;DR: In this paper, the anti-stereochemistry observed in organocuprate SN2′ displacements can be rationalized as a stereoelectronic effect arising from bidentate binding involving a d orbital of nueleophilic copper and π* and σ* orbitals of the substrate.
Journal ArticleDOI

Dynamic stereochemistry of the 5-, 6- and 7-membered rings using the torsion angle notation

E. Toromanoff
- 01 Jan 1980 - 
Related Papers (5)

Direct substitution of hydroxyl groups of allyl alcohols with alkyl groups by the reaction of lithium allyloxyalkylcuprates with N,N-methylphenylaminotriphenylphosphonium iodide. Regio- and stereoselective olefin synthesis

Yoshio Tanigawa, +3 more
- 01 Mar 1977 - 

Conversion of allylic carbamates into olefins with lithium dimethylcuprate. a new formal sn2′ reaction

Carlo Gallina, +1 more
- 01 Feb 1979 - 

Stereochemistry of the SN2' reaction. "Concerted" allylic displacement in an acyclic system: anti displacement with thiolate anion

G. Stork, +1 more
- 01 Mar 1977 - 

Stereochemistry of the SN2' reaction in cyclohexenyl systems

G. Stork, +1 more
- 01 Mar 1977 - 

The stereochemistry of conversion of allylic esters to olefins with lithium dialkylcuprates

Harlan L. Goering, +1 more
- 01 Nov 1976 -