Journal ArticleDOI
Solution synthesis of calcium, strontium and barium metallocenes
TLDR
In this article, the reaction of a cyclopentadienide with a metal halide was used to obtain the THF-soluble complexes (C5H5)2Ca(THF)2 and (Me5C5) 2M(THFs)2 (M = Ca, Sr, Ba).About:
This article is published in Polyhedron.The article was published on 1988-01-01. It has received 46 citations till now. The article focuses on the topics: Cyclopentadienyl complex & Strontium.read more
Citations
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Journal ArticleDOI
Structurally Diverse pi-Cyclopentadienyl Complexes of the Main Group Elements.
Peter Jutzi,Neil Burford +1 more
Patent
Metal complex source reagents for chemical vapor deposition
TL;DR: In this paper, a metal-organic complex of the formula MAYX is defined, wherein M is a y-valent metal; A is a monodentate or multidentate organic ligand coordinated to M which allows complexing of MAy with X; y is an integer having a value of 2, 3 or 4; each of the A ligands may be the same or different.
Journal ArticleDOI
Heavy Grignard Reagents: Challenges and Possibilities of Aryl Alkaline Earth Metal Compounds
TL;DR: First results from quantum chemical calculations on diaryl dicalcium(I) suggest a long Ca-- Ca bond with a considerable Ca--Ca bond dissociation energy.
Journal ArticleDOI
New developments in the organometallic chemistry of calcium, strontium and barium
TL;DR: In this article, different procedures for preparation of complexes d'alcolinoterreux metalloceniques are presented, including caracterisation structurale par diffraction.
Patent
Metal complex source reagents for MOCVD
TL;DR: In this article, a metal organic chemical vapor deposition (MOCVD) source reagents useful for formation of metal-containing films, such as thin film copper oxide high temperature superconductor (HTSC) materials, are described.
References
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Journal ArticleDOI
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
TL;DR: The effective ionic radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are revised to include more unusual oxidation states and coordinations as mentioned in this paper.
Journal ArticleDOI
A New Type of Organo-Iron Compound
T. J. Kealy,P. L. Pauson +1 more
TL;DR: In this article, the reaction of Grignard reagents with anhydrous ferric chloride was studied, but no definite evidence for organo-iron compounds was found in such reactions.
Journal ArticleDOI
Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds
Journal ArticleDOI
Mechanisms of carbon monoxide reduction with zirconium hydrides
TL;DR: In this paper, the authors showed that CO can rapidly displace the N/sub 2/ in 1 to yield a variety of stable adducts, including Olefins, acetylenes, nitriles, isocyanides, and H/Sub 2/ + H/sub2/ + CO. Possible mechanisms for these related reactions are also suggested.