Journal ArticleDOI
A New Type of Organo-Iron Compound
T. J. Kealy,P. L. Pauson +1 more
TLDR
In this article, the reaction of Grignard reagents with anhydrous ferric chloride was studied, but no definite evidence for organo-iron compounds was found in such reactions.Abstract:
NUMEROUS investigators have studied the reaction of Grignard reagents with anhydrous ferric chloride, but have failed to isolate any organo-iron compounds or to produce any definite evidence for their formation in such reactions.read more
Citations
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Journal ArticleDOI
Bioorganometallic Chemistry of Ferrocene
Journal ArticleDOI
Artificial Molecular Rotors
Journal ArticleDOI
Recent applications of chiral ferrocene ligands in asymmetric catalysis.
TL;DR: This Review documents recent advances in asymmetric catalysis, with special emphasis on the most innovative asymmetric processes and the development of novel, efficient types of ferrocene ligands.
Journal ArticleDOI
Energy decomposition analysis
Lili Zhao,Moritz von Hopffgarten,Diego M. Andrada,Gernot Frenking,Gernot Frenking,Gernot Frenking +5 more
TL;DR: The energy decomposition analysis (EDA) is a powerful method for a quantitative interpretation of chemical bonds in terms of three major components as discussed by the authors, which can be interpreted in chemically meaningful way thus providing a bridge between quantum chemical calculations and heuristic bonding models of traditional chemistry.
Journal ArticleDOI
Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations
Baihua Ye,Nicolai Cramer +1 more
TL;DR: A side- and back-wall concept to enforce chirality transfer onto the central metal atom is introduced and Cp(x) derivatives hold promise as powerful steering ligands for further transition-metals used in asymmetric catalysis.
References
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Journal ArticleDOI
Relative Reactivities of Organometallic Compounds. XXV. Coupling Reaction with Halides of Group VIII Metals
Henry Gilman,Myrl Lichtenwalter +1 more
Journal ArticleDOI
Deamination of Certain Amino Derivatives of Sugars and Sugar Alcohols
V. G. Bashford,L. F. Wiggins +1 more
TL;DR: In this article, it was shown that the deamination of certain amino-sugar derivatives leads to the formation of ethylene oxide anhydro sugars from amino sugars.