Journal ArticleDOI
Some complexes containing the dicyclopentadienyl-vanadium(III) group.
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TLDR
The complexes (C 5 H 5 ) 2 V III R, where R pentafluorophenyl, cyclopentadienyl allyl, 2-methylalyl, and 2-butenyl, were prepared by reaction of one mole of (C5 H 5 ), 2 VIII Cl with one Mole of C 5 F 5 Li, C 5H 5 Na, or (methyl)allylmagnesium halide in tetrahydrofuran or diethyl ether as mentioned in this paper.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1968-11-01. It has received 27 citations till now. The article focuses on the topics: Cyclopentadienyl complex & Tetrahydrofuran.read more
Citations
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Open-Shell Organometallics as a Bridge between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity, and Structure.
Journal ArticleDOI
Phenylethynyl complexes of titanocene and vanadocene
TL;DR: In this paper, the synthesis and properties of (C5H5)2VIV(CCC6H5 )2 and diamagnetic complexes were reported.
Journal ArticleDOI
Electron-deficient vanadium(III) alkyl and allyl complexes with amidinate ancillary ligands
TL;DR: In this paper, a vanadium-III amidinate V(III) alkyl and allyl derivatives are derived and compared to the vanadium vanadium (III) amidinate ligands, showing that the substituent pattern of the amidinate ancillary ligand can strongly affect the stability of organometallic derivatives.
Journal ArticleDOI
Some complexes containing the dicyclopentadienylniobium group
TL;DR: The synthesis and properties of the Niobium complexes (π-C 5 H 5 ) 2 NbCl 2, (π -C 5H 5 ), (π C 6 H 5 ), and (π −C 3 H 5, ) are described in this paper.
Journal ArticleDOI
Synthesis and Properties of Aryldicyclopentadienyltitanium(III) Compounds
TL;DR: The synthesis and properties of the compounds Cp2TiR, with R=C6H5, o-, m-, p-CH3C6h4, 2,6-(CH3)2C 6h3, 2.4,6h3C 6H2, C6F5, CH2C6 h5, C 6H4, CH 2C6he5, and CH 2N2N2 are described in this article.
References
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Journal ArticleDOI
Molecular Orbitals for the Protonated Sandwich Compounds.
Journal ArticleDOI
Allyldicyclopentadienyltitanium(III) and (DI)methylallyl homologues
Hendrik A. Martin,F. Jellinek +1 more
TL;DR: Allyldicyclopentadienyltitanium(III) complexes as discussed by the authors have been shown to be monomeric in benzene solution; they have one unpaired electron per molecule.
Journal ArticleDOI
Über Aromatenkomplexe von Metallen, XXXIV. Zur Kenntnis neuer Cyclopentadienyl‐vanadin‐halogenide mit Chlor und Brom
TL;DR: In this article, the Umsetzung von C5H5V(CO)4 mit HBr and O2 konnte nunmehr auch tiefgrunes C5h5VOBr2 erhalten werden, welches schon fruher beschriebenem C5 h5VOCl2 ahnelt.
Journal ArticleDOI
Pentafluorophenyl organometallic compounds of group IV elements
TL;DR: In this article, the synthesis of pentafluorophenyl group IV elements (C 6 F 5 ) 4 Si, C 6 F 6 ) 4 Ge, (C 5 H 5 ) 2 Ti(C 6F 5 ) and Zr(C6 F 5 ).
Journal ArticleDOI
Diallyldicyclopentadienylzirconium and some related complexes
TL;DR: In this paper, the NMR spectra of the 2-methylallyl complexes Cp 2 Zr(C 4 H 7 ) 2 and Cp 4 ZrCl(C 3 H 5 ) 3 were analyzed and compared with corresponding titanium and vanadium complexes.
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Synthesis and properties of alkyldicyclopentadienylvanadium(iii) compounds
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