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Open-Shell Organometallics as a Bridge between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity, and Structure.
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This article is published in Chemical Reviews.The article was published on 1996-10-01. It has received 252 citations till now.read more
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Functional Molecular Flasks : New Properties and Reactions within Discrete, Self-Assembled Hosts
TL;DR: This Review briefly highlights the various molecular flasks synthesized before focusing on their use as functional molecular containers--specifically for the encapsulation of guest molecules to either engender unusual reactions or unique chemical phenomena.
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Two-State Reactivity as a New Concept in Organometallic Chemistry§
TL;DR: The present analysis is based on studies of transition metals under idealized conditions, and several recent reports imply that TSR is by no means confined to the gas phase.
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Fundamentals of H2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H2 Production and Storage
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Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation.
TL;DR: Structural characterization of a high spin iron(0) alkyne and a bis(silane) sigma-complex has been accomplished and in combination with isotopic labeling studies provides insight into the mechanism of both catalytic C-H and catalyticC-Si bond formation.
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Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
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Synthesis and Applications of RuCl2(CHR‘)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity
TL;DR: In this paper, the reactions of RuCl2(PPh3)3 with a number of diazoalkanes were surveyed, and alkylidene transfer was observed for RCHN2 and various para-substituted aryl diazalkanes p-C6H4X CHN2.
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Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media
TL;DR: In this paper, an Ru(II) complex with a strained olefin was used to produce a carbene species that polymerizes norbornene in organic media both in the absence and presence of protic/aqueous solvents.