Journal ArticleDOI
Structures, spectroscopy, and a mechanism of formation of linked-norbornadiene complexes of ruthenium(II). Interaction of ruthenium(II) with alicyclic hydrogen atoms
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This article is published in Journal of the American Chemical Society.The article was published on 1981-06-01. It has received 33 citations till now. The article focuses on the topics: Ruthenium & Norbornadiene.read more
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Journal ArticleDOI
Carbonhydrogen-transition metal bonds
TL;DR: In this article, it was shown that carbon-hydrogen bonds may act as ligands to transition metal centers forming covalent CH⇀M systems in which the H group donates two electrons to the metal.
Journal Article
Carbon-hydrogen-transition metal bonds
Book ChapterDOI
Carbon-Hydrogen-Transition Metal Bonds
TL;DR: In this paper, the agostic C-H-M bond was introduced to discuss the various manifestations of covalent interactions between carbon-hydrogen groups and transition metal centers in organometallic compounds.
Journal ArticleDOI
A New Entry into Molybdenum/Tungsten Sulfur Chemistry: Synthesis and Reactions of Mononuclear Sulfido Complexes of Pentamethylcyclopentadienyl−Molybdenum(VI) and −Tungsten(VI)
TL;DR: A series of mononuclear thio complexes of pentamethylcyclopentadienyl−molybdenum(VI) and −tungsten (VI) have been synthesized via C−S bond-cleaving reactions of thiolates as mentioned in this paper.
Journal ArticleDOI
Bis(1-3:5-6-η-cyclooctadienyl)ruthenium: Preparation, NMR spectroscopy, and isomerization to (η6-1,3,5-cyclooctatriene)(1-2:5-6-η-1,5-cyclooctadiene)ruthenium via the activation of a CH bond
TL;DR: The complex Ru(1-3:5-6-η-C 8 H 11 ) 2 (II) was prepared by the reduction of ruthenium trichloride hydrate with zinc in the presence of 1,5-cyclooctadiene at room temperature.