Journal ArticleDOI
Studies of the polarographic and coulometric behaviour of aromatic nitro-compounds: I. Nitrobenzene in ethanol
TLDR
In this paper, a detailed polarographic and coulometric investigation of nitrobenzene has been made at various pH values in the presence of different concentrations of ethanol, and the results presented in this paper indicate that the first wave in the reduction of n-benzenes is a fourelectron process at all pH values, while the second wave which appears below pH 4.7, corresponds to a two-electron processes irrespective of wave heights.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1969-10-01. It has received 23 citations till now. The article focuses on the topics: Nitrobenzene & Sodium hydroxide.read more
Citations
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Journal ArticleDOI
The electrochemical reduction of nitrobenzene and azoxybenzene in neutral and basic aqueous methanolic solutions at polycrystalline copper and nickel electrodes
TL;DR: In this paper, the electrochemical reduction of nitrobenzene, azoxybenzenes, azobenzene, phenylhydroxyl-amine and hydrazobenzenes was studied at polycrystalline copper and nickel electrodes in neutral and basic aqueous methanolic solutions.
Journal ArticleDOI
The electrocatalytic influence of underpotential lead adsorbates on the reduction of nitrobenzene and nitrosobenzene on silver single crystal surfaces in methanolic solutions
G. Kokkinidis,K. Jüttner +1 more
TL;DR: In this article, the electrocatalytic influence of underpotential lead adsorbates on the reduction of nitrobenzene (φ-NO2) and nitrosobenzenes(φ -NO) on poly-and monocrystalline silver electrodes was studied in methanolic solutions.
Journal ArticleDOI
Recent Advances in the Electrochemical Reduction of Substrates Involving N−O Bonds
Journal ArticleDOI
Double-layer structure and mechanism of electrode reactions: Part II. Nitrobenzene reduction on mercury from aqueous solutions
TL;DR: In this article, different concentrations of non-specifically and specifically adsorbed supporting electrolytes were employed to change the potential φd at the outer Helmholtz plane and/or the charge density qi at the inner Helm-holtz planes.
References
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Journal ArticleDOI
Theorie Langsamer elektrodenreaktionen in der polarographie und polarographisches verhalten eines systems, bei welchem der depolarisator durch eine schnelle chemische reaktion aus einem elektroinaktiven stoff entsteht
Journal ArticleDOI
Electron Spin Resonance and Polarographic Investigation of Substituted Nitrobenzene Negative Ions
August H. Maki,David H. Geske +1 more
TL;DR: In this paper, electron spin resonance spectra were obtained for 14 para substixted nitrobenzene mononegative ions that were generated in acetonitrile solution by electrochemical reduction within a microwave cavity.
Journal ArticleDOI
Electrochemical Generation of Free Radicals and Their Study by Electron Spin Resonance Spectroscopy; the Nitrobenzene Anion Radical
David H. Geske,August H. Maki +1 more
TL;DR: In this paper, the nitrobenzene anion radical (C6H5NO2) was prepared by constant potential electrolysis of nitro benzene solutions at a mercury pool electrode placed directly inside the microwave cavity of an electron spin resonance spectrometer.
Journal ArticleDOI
Electrochemical reduction of pyrimidine, cytosine and related compounds: polarography and macroscale electrolysis
David L. Smith,Philip J. Elving +1 more
TL;DR: The electrochemical reduction of pyrimidine and certain derivatives was investigated over the normal pH range by polarography, coulometry, and macroscale electrolysis as mentioned in this paper, and the reduction products were examined chemically, polarographically, and spectrophotometrically.
Related Papers (5)
Polarography of nitrobenzene in aqueous solutions and in water-alcohol mixtures
H. Sadek,B.A. Abd-El-Nabey +1 more