Journal ArticleDOI
Study of electrophilic substitution reactions at the olefinic carbon atom Communication 4. Kinetics and stereochemistry of the reaction of cis-and trans-β-chlorovinyl-mercury chlorides with iodine in carbon tetrachloride and benzene
TLDR
In this paper, the kinetics of trans-β-chlorovinylmercury chloride with iodine were studied in nonpolar solvents-carbon tetrachlorine and benzene.Abstract:
1.
The kinetics of the reaction of trans-β-chlorovinylmercury chloride with iodine was studied in nonpolar solvents-carbon tetrachlorine and benzene.
2.
In nonpolar solvents the reaction proceeds without conservation of the geometrical configuration. Each of the isomers ofβ-chlorovinylmercury chloride gives the same equimolar mixture of trans- and cis-1,2-chloroiodoethylenes.read more
Citations
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Journal ArticleDOI
Thiocyanatomercuration des acetyleniques. Synthese de derives β-(iso)thiocyanatoalcenyl mercuriques, d'α-halo β-thiocyanato alcenes et de thiocyanato-1 alcynes-1
TL;DR: In the presence of (SCN) − mercuric chloride HgCl 2 adds to acetylenic compounds R 1 CCR 2 affording in most cases α-chloromercuri-β-thiocyanato-1-alkenes as mentioned in this paper.
Book ChapterDOI
Hydrogen and Halogen Substitution
TL;DR: The main focus of most of this work has been on studying the mechanism of electrophilic aliphatic substitution as discussed by the authors, and a number of reviews [1, 2] and one book [5] have appeared covering this topic.
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