Journal ArticleDOI
Synthesis, kinetics, and stereochemistry of the aquation of cis-[chlorosulfitobis(ethylenediamine)cobalt(III)]
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This article is published in Inorganic Chemistry.The article was published on 1989-04-01. It has received 4 citations till now. The article focuses on the topics: Aquation & Ethylenediamine.read more
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Ambidentate ligands, the schizophrenics of coordination chemistry
TL;DR: A broad overview of the physical methods used for structural elucidation of ambidentate ligands can be found in this article, with major emphasis being placed on structures emanating from single crystal X-ray diffraction studies.
Journal ArticleDOI
Sulfite ion substitution of trans-dichlorobis(ethylenediamine)cobalt(III): a classic autocatalytic reaction
TL;DR: In this article, the trans-[Co(en)2Cl2]- complex yields cis-Co-en 2(SO3)Cl cleanly and rapidly via substitution by sulfite ion in water in a rare example of a direct anion substitution process.
Journal ArticleDOI
Synthesis and Characterisation of trans- and cis-[Co(en)2(py)X]n+ (X=Cl, OH, OH2M) and Optical Resolution of the cis Complexes
TL;DR: In this paper, the synthesis of the putative trans -[Co(en)2(py)Cl]2+ complex, isolated as various salts, is reported. And reliable NMR techniques for assigning the NH protons are discussed.