Journal ArticleDOI
Synthesis of (3R,4R)-3-(benzyloxy)-4-(formyloxy)-1-nitro-1-cyclopentene, a chiral synthon for prostaglandin syntheses, from D-glucose
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This article is published in Journal of Organic Chemistry.The article was published on 1986-01-01. It has received 16 citations till now. The article focuses on the topics: Nitro compound & Cyclopentene.read more
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Journal ArticleDOI
The preparation of optically active 2-cyclopenten-1,4-diol derivatives from furfuryl alcohol
TL;DR: Preparation and enzymatic resolution of several cis-mono-4-O-protected-2-cyclopenten-1,4-diols and stereoselective acylation was conducted to afford the corresponding alcohols and acetates in moderate to excellent enantioselectivities.
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Efficient synthesis of 3-substituted indoles through a domino gold(I) chloride catalyzed cycloisomerization/C3-functionalization of 2-(alkynyl)anilines
TL;DR: An efficient synthesis of 3-substituted indoles by a sequential approach involving gold(I) chloride catalyzed cycloisomerization/bis-addition and conjugate addition of 2-(alkynyl)anilines has been accomplished.
Journal ArticleDOI
Mono- and Dialkylation of Derivatives of (1R, 2S)-2-Hydroxycyclopentanecarboxylic Acid and -cyclohexanecarboxylic acid via bicyclic dioxanones: Selective generation of three contiguous stereogenic centers on a cyclohexane ring†‡
Bernardo Herradón,Dieter Seebach +1 more
TL;DR: In this paper, the results of the reduction of 3-oxocyclopentanecarboxylate and cyclohexane carboxylates to bicyclic dioxanone derivatives with formaldehyde, isobutyraldehyde, and pivalaldehyde were reported.
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An Improved Preparation of Highly Enantiomerically Enriched (R)-(+)-4-tert-Butyldimethylsiloxy-2-cyclopenten-1-one.
TL;DR: In this article, a convenient procedure for the preparation of the title compound of ⩾99% ee is presented as well as simple analytical methods for the determination of the optical purity of the product and intermediates in the sequence.
Journal ArticleDOI
Synthesis of 12(S),20-, 12(S),19(R)-, and 12(S),19(S)-dihydroxyeicosa-cis-5,8,14-trans-10-tetraenoic acids, metabolites of 12(S)-hete
TL;DR: In this paper, the 20- and 19-hydroxy metabolites of 12(S)-HETE were synthesized using readily available, chiral precursors, including chiral derivatives.