Journal ArticleDOI
Tetraoxotechnetat(VI) und ‐rhenat(VI)
About:
This article is published in Angewandte Chemie.The article was published on 1974-05-01. It has received 14 citations till now.read more
Citations
More filters
Book ChapterDOI
Technetium Chemistry and Technetium Radiopharmaceuticals
Journal ArticleDOI
Electrochemical reduction of MnO4−, TcO4− and ReO4− in organic solvents: Preparation of tetraoxomanganate(VI), -technetate(VI) and -rhenate(VI)
L. Astheimer,K. Schwochau +1 more
TL;DR: In this paper, the half-wave potentials of permanganate, pertechnetate and perrhenate in organic solvents were obtained in terms of a.c.E.
Journal ArticleDOI
Mechanism and kinetics of the stepwise voltammetric reduction of pertechnetate in alkaline solution to Tc(VI, Tc(V) and Tc(IV)
TL;DR: In this article, the mechanism of the stepwise reduction of TcO−14 to Tc(VI), TcV, and Tc (IV) from pH 9.2 to pH 13.6 was studied by normal pulse polarography and dc polarography.
Book ChapterDOI
The chemistry of technetium: Toward improved diagnostic agents
Mike Clarke,Paul H. Fackler +1 more
TL;DR: In the last five years significant advances have been made in elucidating the chemistry of technetium from a chemical standpoint as discussed by the authors, and a wide range of methods for coordinating chelating nitrogen ligands to Tc(V) offer substantial versatility.
Journal ArticleDOI
Electrochemistry of technetium
TL;DR: In this paper, a review of recent work on the electrochemistry of technetium is presented, covering the period 1973 to 1980, including polarographic and coulometric studies of aqueous pertechnetate at mercury cathodes.
References
More filters
Journal ArticleDOI
Technetium chemistry, oxidation states and species
TL;DR: In this article, the existence of TcO3Cl in aqueous media of 1 N base to 1 N acid has been investigated and no unusual technetium (VII) species has been found.
Journal ArticleDOI
Electronic transitions of permanganate and manganate ions in the near infrared
P. Day,L. Disipio,L. Oleari +2 more
TL;DR: In this article, the existence of weak electronic transitions of MnO − 4 and MnO 2− 4 in the near infrared was confirmed and the Vibrational fine structure of the bands was analyzed and assignments were proposed.
Journal ArticleDOI
Disproportionation of the technetate ion in aqueous alkaline media. An electrochemical study
Journal ArticleDOI
Rhenium and technetium (VI) and meso-(VII) species
TL;DR: This paper showed that less than 35 per cent of normal perrhenate converts to a meso form in 15 M base, and Kf ∼ 0·1, which is probably due to meso (or, ortho) species.