Journal ArticleDOI
The Oxidation Potentials of Aldehydes and Ketones
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This article is published in Journal of the American Chemical Society.The article was published on 1949-11-19. It has received 151 citations till now.read more
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Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis.
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The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
TL;DR: The ternary system consisting of [RuCl2(η6-benzene)]2, N-tosylethylenediamine or ethanolamine, and KOH (Ru:amine:KOH = 1:1:2 molar ratio) catalyzes reversible hydrogen transfer between alcohols and carbonyl compounds.
Journal ArticleDOI
Asymmetric transfer hydrogenation of C=O and C=N bonds
Matthew J. Palmer,Martin Wills +1 more
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Hypervalent iodine reagents as a new entrance to organocatalysts
Toshifumi Dohi,Yasuyuki Kita +1 more
TL;DR: The historical background and the efforts made to realize the catalytic utilization of hypervalent iodine reagents are highlighted, especially with focus on iodine(iii).
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Catalyzed dehydrogenative coupling of primary alcohols with water, methanol, or amines.
TL;DR: The multistep mechanism was elucidated by computational methods and metal-ligand cooperativity is responsible for the high activity of the rhodium amido complex 1 in the dehydrogenative coupling of primary alcohols with water, methanol, or amines to give carboxylic acids, methyl carboxylates, oramides, respectively.
References
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The Fundamental Principles and Applications of Electrolysis with the Dropping Mercury Electrode and Heyrovský's Polarographic Method of Chemical Analysis.
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Oxidation‐Reduction Potentials Measured with the Dropping Mercury Electrode Part I . Studies with Quinhydrone and Estimation of Limits of Measurement
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