Journal ArticleDOI
Topological aspects of the effect of temperature and pressure on the thermodynamics of binary mixtures of non-electrolytes
Reads0
Chats0
TLDR
In this paper, an approach, employing the concept of molecular connectivity index of the third degree of graph theory, has been developed to evaluate molar excess enthalpy, HE(T1, x), and molar capacity VE(T 1, x) of any kind of binary mixture (liquid as well as gaseous) of non-electrolytes.About:
This article is published in Thermochimica Acta.The article was published on 1983-08-01. It has received 101 citations till now.read more
Citations
More filters
Journal ArticleDOI
Thermodynamic studies of molecular interactions in mixtures of o-toulidine with pyridine and picolines: Excess molar volumes, excess molar enthalpies, and excess isentropic compressibilities
TL;DR: In this paper, the authors used the measured densities and speeds of sound data to determine excess molar volumes, VE and excess isentropic compressibilities, κ s E of the investigated mixtures.
Journal ArticleDOI
Molar excess volumes of ternary mixtures of nonelectrolytes
TL;DR: In this article, the authors examined the data in terms of Sanchez and Lacombe theory and the graph-theoretical approach, and it was found that they are described well by the latter.
Journal ArticleDOI
Thermodynamic properties of binary mixtures of the ionic liquid [emim][BF4] with acetone and dimethylsulphoxide
TL;DR: In this article, the Graph theory has been applied to calculate the topology of the constituents of ionic liquid mixtures in their pure and mixed state; the nature and extent of interactions existing in mixtures; and the VE, HE and κ S E values.
Journal ArticleDOI
Thermodynamic and Topological Studies of 1-Ethyl-3-methylimidazolium Tetrafluoroborate + Pyrrolidin-2-one and 1-Methyl-pyrrolidin-2-one Mixtures
TL;DR: In this paper, the topology of the constituents of mixtures (graph theory) has been employed to calculate the VE, HE, and κSE of ionic liquid mixtures and the analysis of the measured data in terms of graph theory suggests that investigated (1 + 2) mixtures are characterized by interactions forming a 1:1 molecular complex.
Journal ArticleDOI
Excess heat capacities of 1-methyl pyrrolidin-2-one and pyridine or picolines mixtures
Vinod Kumar Sharma,A. Rohilla +1 more
TL;DR: In this article, the excess heat capacities of binary 1-methyl pyrrolidin-2-one (i) + pyridine or α- or β- or γ-picoline (j) mixtures have been measured as a function of composition at 293.15, 298.15 and 303.15 k using micro differential scanning calorimeter (Model-μDSC 7 Evo).
References
More filters
Journal ArticleDOI
An elementary molecular theory of classical fluids. Pure fluids
Journal ArticleDOI
Regular and Related Solutions
TL;DR: Goodwin and Wojciechowski as mentioned in this paper discuss den EinfluB einer reversiblen Chemisorption auf die elektrischen Leitfáhigkeit eines n-Halbleiters, and überprüfen im zweiten Teil die theoretischen Ergebnisse anhand experimentellen Materials, das sie bei der Sauerstoffadsorption an dünnen CtfS-Proben gesammelt haben.