Journal ArticleDOI
Trans-[(en)2Co(Cl)(S2O3)], Na[trans-[(en)2Co(C2O4)(S2O3)]], trans-[(en)2Co(NCO)(S2O3)], and the nature of [(en)2Co(OH2)(S2O3)]+ in aqueous solution
J. N. Cooper,J. G. Bentsen,T. M. Handel,K. M. Strohmaier,W. A. Porter,B. C. Johnson,A. M. Carr,D. A. Farnath,S. L. Appleton +8 more
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This article is published in Inorganic Chemistry.The article was published on 1983-10-01. It has received 5 citations till now. The article focuses on the topics: Aquation & Carboxylate.read more
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Journal ArticleDOI
Ambidentate ligands, the schizophrenics of coordination chemistry
TL;DR: A broad overview of the physical methods used for structural elucidation of ambidentate ligands can be found in this article, with major emphasis being placed on structures emanating from single crystal X-ray diffraction studies.
Journal ArticleDOI
Synthesis and structure of some cobalt(II), cobalt(III) and one nickel(II) monomeric, monodentate(S) thiosulfato complexes. Trans and cis structural effects in the cobalt(III) complexes.
Alan Carter,Michael G. B. Drew +1 more
TL;DR: The crystal structures of five monomeric complexes with monodentate thiosulfato-S ligation have been determined in this paper, and the structures are centrosymmetric with the metals in octahedral environments.
Book ChapterDOI
Substitution Reactions of Inert Metal Complexes—Coordination Numbers 6 and Above: Cobalt
TL;DR: A general discussion of the chemistry of cobalt(III) complexes covering the 1981 literature can be found in this article, with an excellent review by Tobe(2) on the base hydrolysis of metal complexes.
Journal ArticleDOI
Trans-((en)2co(cl)(s2o3)), na(trans-((en)2co(c2o4)(s2o3))), trans-((en)2co(nco)(s2o3)), and the nature of ((en)2co(oh2)(s2o3))+ in aqueous solution
J. N. Cooper,J. G. Bentsen,T. M. Handel,K. M. Strohmaier,W. A. Porter,B. C. Johnson,A. M. Carr,D. A. Farnath,S. L. Appleton +8 more
Journal ArticleDOI
Kinetics and mechanism of the anation of (αβ)-hydroxo(tetraethylenepentamine)cobalt(III) by thiosulfate, the base hydrolysis of the (sulfur-bonded) thiosulfato(tetraethylenepentamine)-cobalt(III) and photochemistry of oxygen and sulfur-bonded thiosulfato complexes
TL;DR: In this paper, the reaction of (αβ)-(tetren)CoOH2+ with S2O32-in the 7.25-8.28 pH range at 20 −40 °C yielded S- (yellow) and O- (purple) bonded thiosulfato(tren)cobalt(III) complexes, the former in larger quantities.