Book ChapterDOI
Transition Metal Complexes Containing Bridging Alkylidene Ligands
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This article is published in Progress in Inorganic Chemistry.The article was published on 2007-03-09. It has received 31 citations till now. The article focuses on the topics: Carbene & Chemical reaction.read more
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Multiple Bonds between Transition Metals and “Bare” Main Group Elements: Links between Inorganic Solid State Chemistry and Organometallic Chemistry
TL;DR: In this article, a review of metal-metal multiple-bond structures with substituent-free (bare) main group elements can be found in the context of preconditioned organometallic chemistry.
Journal ArticleDOI
Essays on organometallic chemistry, VII. Laboratory curiosities of yesterday, catalysts of tomorrow: organometallic oxides
TL;DR: A systematic investigation of organorhenium and organoosmium oxides was conducted by Herrmann, Serrano and Bock as discussed by the authors, who solved general problems related to synthesis and reactivity, to structure and bonding, as well as to thermal and photochemical stability.
Book ChapterDOI
Alkyne-Substituted Transition Metal Clusters
Paul R. Raithby,Maria J. Rosales +1 more
TL;DR: In this article, the synthesis, characterization, structure, and reactivity of transition metal clusters containing alkyne or alkynes-derived ligands are discussed, and the main difference between the reactions of high-nuclearity clusters with alkynes and alkenes and those of the smaller clusters is that the addition of the organic fragment can produce the rupture of metal-metal bonds without cluster breakdown.
Journal ArticleDOI
Mehrfachbindungen zwischen Übergangsmetallen und “nackten” Hauptgruppenelementen: Brücken zwischen der anorganischen Festkörperchemie und der Organometallchemie
TL;DR: In this article, we refer to the article "Metall-metall-mehrfachbindungssysteme als Katalysatoren" for an overview.
Journal ArticleDOI
Stoichiometric C═O bond oxidative addition of benzophenone by a discrete radical intermediate to form a cobalt(I) carbene.
TL;DR: In this paper, thermolysis of 2 in an attempt to favor a monomeric ketyl radical species unexpectedly led to cleavage of the C-O bond to generate a Zr/Co μ-oxo species featuring an unusual terminal Co−CPh2 carbene linkage.
References
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Olefin homologation with titanium methylene compounds
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Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques
TL;DR: On propose un schema reactionnel en accord avec les faits observes dans la reaction de disproportion des olefines acycliques, la polymerisation des ollines cycliques, the telomerisation of l'olefine cyclique, and the polymerisation of olline cycliques by les olefine acyCLiques as discussed by the authors.
Book ChapterDOI
Ziegler-Natta Catalysis
Hansjörg Sinn,Walter Kaminsky +1 more
TL;DR: In this article, the authors discuss the scope of Ziegler catalysis, stereoselectivity, kinetics, and mechanism of homogeneous Natta catalysts; and side reactions in homogeneous catalysts.
Journal ArticleDOI
On the Existence of a Tungsten Carbonyl Carbene Complex
E. O. Fischer,A. Maasböl +1 more