Journal ArticleDOI
Unusual spin-transition anomaly in the crossover system [Fe(2-pic)3]Cl2·EtOH
TLDR
The spin transition in [Fe(2pic) 3 ]Cl 2 ·EtOH (2-pic = 2-picolylamine) has been reinvestigated by Mossbauer spectroscopy and magnetic susceptibility measurements as mentioned in this paper.About:
This article is published in Chemical Physics Letters.The article was published on 1982-09-24. It has received 123 citations till now. The article focuses on the topics: Spin crossover & Spin transition.read more
Citations
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Journal ArticleDOI
Spin state switching in iron coordination compounds
TL;DR: The article deals with coordination compounds of iron(II) that may exhibit thermally induced spin transition, known as spin crossover, depending on the nature of the coordinating ligand sphere, and the variety of physical techniques usually applied for their characterization.
Book ChapterDOI
Light-induced spin crossover and the high-spin→low-spin relaxation
TL;DR: The discovery of light-induced spin transition at cryogenic temperatures in a series of iron(II) spin-crossover compounds in 1984 has had an enormous impact on spin crossover research as mentioned in this paper.
Journal ArticleDOI
Thermisch und optisch schaltbare Eisen(II)‐Komplexe
TL;DR: In this paper, Eisen(II)-Spincrossover-Verbindungen ein, in denen der Spinubergang im Festkorper auf sehr unterschiedliche Weise - graduell, abrupt, mit Hysterese oder stufenweise - verlaufen kann and mit Mosbauer-and optischer Spektroskopie, with magnetischen Suszeptibilitats-and Warmekapazitatsmessungen, intensiv untersucht word
Journal ArticleDOI
Spin Crossover Nanomaterials: From Fundamental Concepts to Devices
TL;DR: In this progress report, a brief overview on the current state-of-the-art of experimental and theoretical studies of nanomaterials displaying spin transition is presented, and detailed analysis and discussions in terms of finite size effects and other phenomena inherent to the reduced size scale are provided.
Journal ArticleDOI
The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands
TL;DR: A survey of mononuclear iron(II) complexes with heterocyclic N-donor ligation is presented in this paper, where a brief introduction to spin-crossover chemistry and low-temperature spin-trapping is provided, since many of these compounds undergo thermal spintransitions upon cooling or heating.
References
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Journal ArticleDOI
The effect of the lattice expansion on high spin ⇌ low spin transitions
TL;DR: In this paper, the dilution effect on the high spin (HS) ⇌low spin (LS) transition in [FexZn1−x(2-pic)3]Cl2 · EtOH has been studied on the basis of the theory of elastic interactions of the HS and LS molecules of iron (II) and zinc complexes in the crystal.
Journal ArticleDOI
Mössbauer effect study on low-spin 1A1 ⇌ high spin 5T2 transition in [Fe(2-pic)3]Cl2: II. Influence of non-coordinating solvent molecule in [Fe(2-pic)3] Cl2 · X1 X = C2H5OH, CH3OH, H2O and 2H2O
TL;DR: The 57Fe Mossbauer effect of solvated tris(2-aminomethylpyridine) iron (II) chloride has been studied in detail between 80 and 310 K as discussed by the authors.
Journal ArticleDOI
Molecular transformations in the solid state. Crystallographic resolution of the spin isomers of tris(2-picolylamine)iron(II) dichloride and the structural relationship between the methanol and ethanol solvates
Journal ArticleDOI