Journal ArticleDOI
Visible light promoted cross-dehydrogenative coupling: a decade update
Avik Kumar Bagdi,Matiur Rahman,Dhananjay Bhattacherjee,Grigory V. Zyryanov,Grigory V. Zyryanov,Sumit Ghosh,Oleg N. Chupakhin,Oleg N. Chupakhin,Alakananda Hajra +8 more
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TLDR
The use of renewable energy resources without the need for prefunctionalization of the reactant synergistically promote the synthetic pathway towards green synthesis as discussed by the authors. But the applicability and mechanistic pathways of the methodologies have been also discussed.About:
This article is published in Green Chemistry.The article was published on 2020-10-19. It has received 105 citations till now.read more
Citations
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Cross-dehydrogenative coupling: a sustainable reaction for C–C bond formations
Tian Tian,Zhiping Li,Chao-Jun Li +2 more
TL;DR: The cross-dehydrogenative coupling (CDC) reaction has been widely developed as one of the most sustainable and efficient synthesis strategies for constructing C-C bonds as mentioned in this paper, and a review summarizes the development of this field over the past 20 years, with a discussion on future trends and directions.
Journal ArticleDOI
Photoelectrochemical cross-dehydrogenative coupling of benzothiazoles with strong aliphatic C-H bonds.
TL;DR: A photoelectrochemical strategy for the cross-dehydrogenative coupling of unactivated aliphatic hydrogen donors with benzothiazoles with tetrabutylammonium decatungstate as the photocatalyst to activate strong C(sp3)-H bonds in the chosen substrates, while electrochemistry scavenged the extra electrons.
Journal ArticleDOI
Direct para-C–H heteroarylation of anilines with quinoxalinones by metal-free cross-dehydrogenative coupling under an aerobic atmosphere
TL;DR: In this paper, a green and efficient cross-dehydrogenative coupling for the direct para-C-H heteroarylation of anilines with quinoxalinones has been described.
Journal ArticleDOI
Electrochemical Functionalization of Imidazopyridine and Indazole: An Overview
Journal ArticleDOI
Sulfonylation of Aryl Halides by Visible Light/Copper Catalysis.
TL;DR: In this paper, an efficient visible-light-assisted, copper-catalyzed sulfonylation of aryl halides with sulfinates with a single ligand CuI photocatalyst formed in situ was used in the photocatalytic transformation.
References
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Journal ArticleDOI
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
TL;DR: The conversion of these bench stable, benign catalysts to redox-active species upon irradiation with simple household lightbulbs represents a remarkably chemoselective trigger to induce unique and valuable catalytic processes.
Journal ArticleDOI
Organic Photoredox Catalysis
TL;DR: An overview of the basic photophysics and electron transfer theory is presented in order to provide a comprehensive guide for employing this class of catalysts in photoredox manifolds.
Journal ArticleDOI
Catalytic dehydrogenative cross-coupling: forming carbon-carbon bonds by oxidizing two carbon-hydrogen bonds
Charles S. Yeung,Vy M. Dong +1 more
Journal ArticleDOI
Green Chemistry: Principles and Practice
Paul T. Anastas,Nicolas Eghbali +1 more
TL;DR: The concepts of design and the scientific philosophy of Green Chemistry are covered with a set of illustrative examples and the challenge of using the Principles as a cohesive design system is discussed.
Journal ArticleDOI
Cross-dehydrogenative coupling (CDC): exploring C-C bond formations beyond functional group transformations.
TL;DR: This work over the past several years to form carbon-carbon bonds directly from two different C-H bonds under oxidative conditions, cross-dehydrogenative coupling (CDC) is described, which provides an alternative to the separate steps of prefunctionalization and defunctionsalization that have traditionally been part of synthetic design.
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Cross-dehydrogenative coupling (CDC): exploring C-C bond formations beyond functional group transformations.
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Charles S. Yeung,Vy M. Dong +1 more