scispace - formally typeset
Search or ask a question

Coordinations compounds chemistry ? 


Best insight from top research papers

Coordination compounds chemistry is a broad field of inorganic chemistry that focuses on the formation of coordinate bonds between metal atoms or ions and electron pair donors. These compounds involve the acceptance of electron pairs from molecules or ions by a metal ion or atom. Coordination compounds have potential applications in various fields such as adsorption, separation, catalysis, and electrical, magnetic, and optical applications . The use of coordination chemistry in lithium-ion batteries (LIBs) and lithium–metal batteries (LMBs) has gained attention for improving their energy and power densities, cycle life, and performance . Additionally, coordination compounds can be used as ligands in the construction of coordination polymers, which have potential applications in the development of porous materials . The design and synthesis of coordination compounds and coordination polymers involve various strategies, such as self-assembly, solvothermal/hydrothermal reactions, and postsynthetic modifications . Overall, coordination compounds play a crucial role in the development of functional materials with diverse applications.

Answers from top 5 papers

More filters
Papers (5)Insight
OtherDOI
17 Jun 2022
3 Citations
The paper provides an overview of the coordination chemistry of porphyrins and other porphyrinoids, including methods for metallation, demetallation, and characterization of complexes. It also discusses the coordination chemistry of main group elements, transition metals, lanthanides, and actinides.
Book ChapterDOI
James E. House, Kathleen A. House 
01 Jan 2010
1 Citations
The paper discusses the chemistry of coordination compounds, which involves the formation of coordinate bonds between metal atoms or ions and electron pair donors.
Book ChapterDOI
M.-L. Tong, X.-M. Chen 
01 Jan 2017
12 Citations
The paper discusses the synthetic methods and molecular design of coordination compounds, as well as factors influencing their self-assembly and crystallization. It also mentions solvothermal/hydrothermal reactions and postsynthetic modifications for coordination polymers.
The paper discusses the synthesis and properties of a series of coordination compounds containing 2,4,6-oxy functionalized 1,3,5-triphosphinines as ligands. The ligand properties can be tuned by changing the substituent on the oxygen center.
The paper discusses the applications of coordination chemistry in lithium-ion batteries and lithium-metal batteries, focusing on the development of electrode and electrolyte materials based on coordination compounds.

Related Questions

What are intermetallic compounds?5 answersIntermetallic compounds are a diverse class of materials formed by the combination of over 80 metallic elements, showcasing unique crystal structures distinct from traditional alloys. These compounds exhibit a blend of physical and mechanical properties like high melting points, low density, and good resistance to oxidation and creep, although they can be brittle at room temperature. Advances since the 1980s have enhanced the ductility of specific intermetallics through alloying and microstructural control, expanding their industrial applications. Liquid-phase synthesis has emerged as a precise method for creating intermetallics with controlled structures, stoichiometry, and resistance to sintering, making them attractive for catalytic applications. The presence of intermetallic compounds in high-temperature processing materials is anticipated to benefit industries like aerospace, automotive, and electronics.
What compounds have a block structure?5 answersVarious compounds with block structures have been reported in the provided abstracts. One paper describes the synthesis of block molecules composed of a hexa-peri-hexabenzocoronene (HBC) core and two oligo(dimethylsiloxane) (ODMS) tails, which form a hierarchical lamello-columnar structure with a two-dimensional rectangular lattice. Another paper discusses a compound sliding block structure in a die casting mold, which includes a compound sliding block composed of a driven sliding block and a bottom basic sliding block. Additionally, a paper mentions the synthesis of block-like molecules based on the stereochemistry of tertiary aromatic amide, which exhibit various shapes such as triangular, rhombic, twisted, spherical, or pinched circle. Therefore, these papers provide examples of compounds with block structures, including those used in nanotechnology, die casting molds, and stereochemistry studies.
Are there any other interesting aspects about the structures of these compounds?5 answersThe structures of the compounds mentioned in the abstracts exhibit various interesting aspects. In the case of lanthanide complexes with adipate and aqua ligands, the crystal structures show a variety of topologies and dimensionality, with different metal chains or dinuclear Ln2 entities connected by carboxylate groups. Organosilicon compounds, which have silicon atoms replacing carbon atoms in organic molecules, maintain their architecture due to the close similarity between silicon and carbon. Cyclodextrins, specifically α-, β-, and γ-cyclodextrins, form inclusion complexes with guest molecules and exhibit different conformations and host-guest interactions, including London dispersion forces and hydrogen bonding. X-ray crystallography is a valuable method for determining the arrangement of atoms within a crystal and provides information about chemical bonds and electron density. The crystal structures of organoselenium compounds reveal specific geometries around the selenium atom, such as T-shaped or cisoid conformations.
How can chemical compound be described of chemical compound?5 answersChemical compounds can be described using structure-derived descriptors and chemical ontologies. These methods help classify compounds into different compound classes based on their structural and property features. MeSH and ChEBI are examples of chemical ontologies that provide hierarchical classifications of compounds. Manual classification of compounds is time-consuming and error-prone, so automated and comprehensive classification methods are needed. The use of SMARTS expressions and structure-based reasoning logic allows for precise and granular class definitions in chemical ontologies. Integration with a chemical structure search engine enables the automated assignment of compounds to ontology classes. Additionally, natural language processing methods can be used to match synonymic names of chemical compounds, facilitating the identification and annotation of compounds in databases and literature.
What is the chemical formula for a chemical compound?3 answersThe chemical formula for a chemical compound can vary depending on the specific compound being referred to. In general, chemical formulas are used to represent the composition of a compound in terms of the elements present and their respective ratios. The abstracts provided mention different chemical formulas for various compounds. For example, one abstract mentions a compound represented by formula 1, where R can represent different groups such as hydrogen, alkyl, alkoxy, aryl, or silyl. Another abstract describes a compound represented by a general formula (I), where R and Ris different alkylene groups. Yet another abstract mentions compounds represented by formulae (11) to (13), with various groups represented by different formulas. Additionally, two abstracts discuss a chemical compound with a first bivalent structural unit and a second bivalent structural unit, with specific formulas and substituents. Therefore, the chemical formula for a compound depends on its specific structure and composition.
Is chelate and ligand same?8 answers