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Is there any ligand based on anisaldehyde and 2,4 diaminoanisole? 


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There is no ligand based on anisaldehyde and 2,4-diaminoanisole mentioned in the provided abstracts.

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The ligand based on anisaldehyde and 2,4 diaminoanisole is not mentioned in the provided information.

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What is ligand?5 answersA ligand is a small molecule that forms a complex with a biomolecule to serve a biological purpose. The binding occurs through intermolecular forces such as ionic bonds, hydrogen bonds, and van der Waals forces. Ligands can have different structures and functionalities. For example, ligands can contain a spacer and two tridentate groups, which can be used in metallo-polymers. Ligands can also contain a benzimidazole skeleton with functional groups capable of forming a coordinate bond with a metal. Ligands are important in various fields, including biochemistry, pharmacology, and materials science. In materials science, ligands are used in the construction of metal-organic frameworks with different connectivities and levels of interpenetration. Overall, ligands play a crucial role in molecular interactions and have diverse applications in different scientific disciplines.
How can anisaldehyde and 4 nitroaniline be used to create a ligand?2 answersAnisaldehyde can be used to create a ligand by reacting it with suitable aldehydes under reductive conditions. Chiral amines can also be used in this process. The resulting ligands based on an imidazole ring with an additional (hetero)ring show strong hydrogen bonds in solution, leading to hindered imidazole tautomerism. These ligands have been applied as ligands in copper (II)-catalyzed nitroaldol reactions, specifically the Henry reaction, and have shown fast reaction times and a reversal in enantioselectivity compared to other chiral amines. However, there is no mention of using 4-nitroaniline specifically in the creation of these ligands in the provided abstracts.
Are there any ligands based on anisaldehyde and 2,4 diaminotoluene?1 answersThere are ligands based on anisaldehyde and 2,4-diaminotoluene. These ligands were prepared by reacting chiral amines with suitable aldehydes, including 2-phenylimidazole-4-carbaldehyde and 2-hydroxybenzaldehyde, under reductive conditions. However, there is no mention of ligands specifically based on 2,4-diaminotoluene in the provided abstracts.

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