What is a heteroleptic coordination cage?
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A heteroleptic coordination cage is a type of supramolecular structure that is built from non-covalent coordination bonds and contains multiple ligand types or mixed-metal compositions . These cages have a confined cavity, similar to the binding pocket of an enzyme, and can be used to bring substrates closer together for interaction and exhibit non-classical physical properties . They offer a diverse platform for enzyme mimics and have the potential for substrate recognition, transition-state stabilization, and product release . Heteroleptic coordination cages can also be used for asymmetric catalysis, creating an asymmetric microenvironment for enantioselective transformations . They have been shown to exhibit excellent enantioselective separation of racemic compounds and commercially available drugs . These cages are a promising area of research in the field of catalysis, offering unique structures and tunable properties not available to traditional catalysts .
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34 Citations | The text does not provide information about a heteroleptic coordination cage. |
17 Citations | A heteroleptic coordination cage is a type of coordination cage that contains different types of ligands coordinated to the metal ions. |
84 Citations | The term "heteroleptic coordination cage" is not mentioned in the provided text. |
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49 Citations | The text does not provide information about heteroleptic coordination cages. |
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