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What is the relationship between magnetoelasticity and the microstructure of grains in BiFeO3? 


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The relationship between magnetoelasticity and the microstructure of grains in BiFeO3 is significant. Studies on BiFeO3 powders sintered by flash and spark plasma sintering revealed that a phase transition anomaly at 250 K is linked to magneto-elastic coupling, becoming less defined as grain sizes decrease . Additionally, BiFeO3-GdMnO3 solid solutions exhibited enhanced ferromagnetic properties with increasing GdMnO3 concentration, showcasing a strong magnetodielectric coupling . Furthermore, the magnetization of BiFeO3 powders synthesized through conventional sintering and ball milling correlated linearly with grain size, indicating finite size effects and the presence of exchange bias . The chemical composition variations in Bi1−xAexFe1−xTixO3 solid solutions influenced their crystal structure and magnetic behavior, with certain substitutions stabilizing weak ferromagnetic ferroelectric states .

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The Bi-excess in BiFeO3 nanoparticles influences magnetoelasticity, with Bi0.05FeO3 showing weak ferromagnetic behavior and a maximum saturation magnetization of 0.24 emu/g.
Variations in chemical composition in BiFeO3-based multiferroics influence crystal structure and magnetic behavior, showcasing a tight coupling between magnetostructural correlations in grains.
The magnetization of BiFeO3 powders is influenced by the grain size, showing a linear relationship with the reciprocal of the grain size due to the finite size effect.
The microstructure of grains in BiFeO3 influences magnetoelastic properties, as shown in the study on BiFeO3-GdMnO3 multiferroics, indicating a relationship between microstructure and magnetoelasticity.
The magnetoelastic coupling in BiFeO3 is linked to grain size reduction, affecting the clarity of the low-temperature phase transition, as observed in flash and spark plasma sintering methods.

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