What is the relationship between the Boltzmann factor and the activation energy of a reaction?
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The relationship between the Boltzmann factor and the activation energy of a reaction is that a lower activation energy corresponds to a higher Boltzmann factor, indicating a higher probability of reaction occurrence . This relationship is observed in the reactions of linear and monomethyl-branched alkanes over various catalysts, where lower activation energies are associated with higher pre-exponential factors . Additionally, in oscillating reactions, increasing the flow rate leads to a decrease in the oscillatory activation energy, approaching a limit value . The sensitivity of the oscillatory activation energy to the flow rate is described by the parameter η, which characterizes the correlation between the dynamical behavior and temperature . Therefore, the Boltzmann factor and activation energy are interconnected in determining the likelihood and dynamics of chemical reactions .
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