How does tannin stop fire?5 answersTannin acts as a fire retardant through various mechanisms depending on its application. In the case of tannin-based materials like tannin foams and coatings, the carbonaceous nature of tannin allows it to form a protective char layer when exposed to fire, which insulates the underlying material and prevents further combustion. This char layer acts as a barrier, limiting the access of oxygen to the material and reducing the release of flammable volatiles, thus inhibiting the spread of fire. Additionally, tannin-based materials exhibit good thermal stability at high temperatures, further enhancing their fire resistance properties. The use of tannin in fire-resistant coatings and foams has shown promising results in improving the fire-retardant capabilities of various materials, making them more suitable for applications requiring enhanced fire protection.
How does tannins affect pH level?5 answersTannins can influence pH levels in various ways. Research shows that tannin pH values can impact the physical and thermochemical properties of tannin foams, with acidic tannin extracts yielding lightweight and hydrophobic foams. Additionally, tannins and pH are linked to the corrosiveness of wood, where increasing tannin content inhibits corrosion, and lower pH levels increase corrosion rates. Moreover, the effects of pH on tannin-induced astringency and tannin-salivary protein interactions reveal that tannins are perceived as more astringent at lower pH levels, exacerbating their effects on protein interactions. Furthermore, in plant systems, changes in soil nutrient supply have a greater influence on secondary compound production, including tannins, than alterations in solution pH.
Are there any studies analyzing the leaching of tannin films?5 answersStudies have been conducted to analyze the leaching of tannins in various forms. Research has shown that tannin-based natural coagulants can effectively remove organic compounds and heavy metals from stabilized landfill leachate. Additionally, investigations have been carried out on the leaching of lignin and tannins from raw Emblica officinalis leaf powder, indicating a pseudo second-order kinetics for the leaching process. Furthermore, studies comparing different woodchip types as denitrifying bioreactor media have shown that oak initially leaches higher concentrations of tannic acid, true color, and chemical oxygen demand (COD) compared to other wood types, but these differences diminish over time. Moreover, tannin copolymer formulations have been developed for wood preservation, demonstrating improved leaching resistance and resistance against biological attacks.
How NaOH affect the water pH level?5 answersNaOH, or sodium hydroxide, plays a crucial role in adjusting water pH levels in various applications. In abalone culture systems, NaOH addition raised pH levels, positively correlating with weight gain and length gain of H. midae. In desalination processes, dosing NaOH into feed streams can induce controlled pH increases, but high local concentrations may lead to precipitation issues. In the supercritical water oxidation process, pre-dosed NaOH affected the conversion rate of 2,4-DCP, with higher amounts improving the rate but potentially causing fouling problems. Additionally, in aquaculture, molecular analysis revealed that O2 accelerated pH recalibration in seawater when NaOH was added, particularly in alkaline conditions, suggesting a potential alternative for pH maintenance in aquaculture systems. Furthermore, in corrosion studies, NaOH acted as an anodic inhibitor, reducing the corrosion rate of mild steel as pH levels increased.
How condensed tannin act as an antioxidant?5 answersCondensed tannins (CTs) act as antioxidants through various mechanisms. They can improve the antioxidant status in animals and enhance the oxidative stability of their products by direct and indirect means, such as absorption with low molecular weight metabolites, antioxidant action in the gastrointestinal tract, and interaction with other antioxidants. Additionally, CTs extracted from natural sources like Euonymus laxiflorus exhibit high antioxidant capacity and can inhibit oxidative stress effectively. Furthermore, CTs from longan pericarps and seeds show significant antioxidant and antibacterial activities, making them suitable for use as natural preservatives in fresh-cut fruits and vegetables. In plants like poplar, stress-induced CTs increase antioxidant activity, protecting against oxidative stress and suggesting a broader role for CTs as in vivo antioxidants. Tannin-enriched extracts from Ecklonia cava also demonstrate antioxidant effects by modulating oxidative stress and muscarinic cholinergic regulation, contributing to laxative effects in chronic constipation models.
How does pH affects tannin content?4 answerspH plays a crucial role in influencing tannin content in various contexts. Lower pH levels have been associated with higher tannin concentrations, as observed in wine studies where wines with pH 3.2 exhibited more rapid changes in tannin structure compared to pH 3.8 wines. Additionally, tannin sources like rock rose and grape seed have shown the ability to bind to proteins at pH 6-8, reducing protein solubility, which can protect proteins from excessive rumen degradation in ruminants. Moreover, in tannin-based foams, acidic tannin extracts below pH 4.8 yielded foams with lightweight and hydrophobic properties, indicating that pH influences the physical characteristics of tannin foams. Therefore, pH variations impact tannin content in wine, protein binding, and foam properties, showcasing the diverse effects of pH on tannins.