Showing papers on "Gibbs–Helmholtz equation published in 1975"
TL;DR: In this article, the thermodynamic equilibrium Sn(l + O2(g) = SnO2(s) has been studied between 773 and 1380 K by e.m.f. measurements on cells involving a solid electrolyte.
23 citations
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8 citations
01 Dec 1975-Metallurgical and Materials Transactions B-process Metallurgy and Materials Processing Science
TL;DR: In this paper, a relationship between the length of this intersection and the Gibbs free energy for the reciprocal reaction of the pure solids has been derived, and calculated values from experimental results are compared with data from free energy tables and show good agreement.
Abstract: In the phase diagrams of reciprocal systems with negligible solubilities in the solid state the liquidi of the stable pair intersect. A relationship between the length of this intersection and the Gibbs free energy for the reciprocal reaction of the pure solids has been derived. Calculated values from experimental results are compared with data from free energy tables and show good agreement.
5 citations
3 citations
TL;DR: In this paper, the infinite coupling constant limit of the resolvent, the semigroup and the Gibbs state is obtained for a certain class of perturbations for the one-dimensional Hubbard model with nearest neighbour hopping terms.
Abstract: The infinite coupling constant limit of the resolvent, the semigroup and the Gibbs state is obtained for a certain class of perturbations. As an example the infinite intrasite repulsion limit of the one-dimensional Hubbard model with nearest neighbour hopping terms is treated. This system exhibits a phase transition in the thermodynamic limit.
1 citations